dichlorobis(tetrazol-2-ylacetate)platinum(II) | 1241667-70-8

• 英文名称: dichlorobis(tetrazol-2-ylacetate)platinum(II)
• CAS: 1241667-70-8
• 化学式: C₆H₈Cl₂N₈O₄Pt
• 分子量: 522.167
• InChiKey: WUBFIBPLGTZQDN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 2H-四唑-2-乙酸 以 水 为溶剂， 以36%的产率得到dichlorobis(tetrazol-2-ylacetate)platinum(II)
  参考文献：
  名称：

  Preparation and characterization of the first coordination compounds of tetrazol-2-ylacetic acid

  摘要：

  Tetrazol-2-ylacetic acid (2-TzaH) was found to react with CuCl2, PdCl2, and K2PtCl4 in water giving Cu(2-Tza)(2), PdCl2(2-TzaH)(2)center dot 2H(2)O and PtCl2(2-TzaH)(2), correspondingly. Obtained complexes, being the first reported examples of coordination compounds derived from 2-TzaH, have been characterized by IR spectroscopy, thermal and X-ray diffraction methods. 2-TzaH was found to act as a monodentate ligand coordinated to the metal ion via N4 atom of heteroring in palladium complex and as tridentate bridging ligand coordinated via N4 atom and two oxygen atoms in copper complex. Cu(2-Tza)(2) presents 2D coordination polymer, whereas PdCl2(2-TzaH)(2)center dot 2H(2)O is molecular complex. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.05.003