cis-[ReBr4(acetonitrile)2] | 56602-28-9

• 英文名称: cis-[ReBr4(acetonitrile)2]
• CAS: 56602-28-9
• 化学式: C₄H₆Br₄N₂Re
• 分子量: 587.928
• InChiKey: KRAOEPUNVUTSFV-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  (NBu₄)₂[ReBr₆] 、 乙腈 以 乙腈 为溶剂， 生成 cis-[ReBr4(acetonitrile)2]
  参考文献：
  名称：

  Photosolvation reactions of hexabromorhenate(IV)

  摘要：

  In acetonitrile and tetrahydrofuran solutions, irradiation of [ReBr6](2) leads to the replacement of a bromide by a solvent molecule, followed at a much slower rate by the photosolvation of a second bromide. The quantum yield for the primary photosolvation is 0.013 in CH3CN. As an alternative to photolysis occurring through a doublet d-d excited state, it is suggested that excitation of the charge transfer bands may cause photodissociation, followed by coordination of a solvent molecule and reoxidation to the. final product. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.03.119