| 185010-22-4

• CAS: 185010-22-4
• 化学式: C₆₀H₈₆Au₂Cl₂N₄O₆
• 分子量: 1424.21
• InChiKey: KBNKIBPLGQHSKB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  chloro[4-((4'-(n-dodecyloxy)phenyl)carbonyl)phenyl isonitrile]gold 、 N,N'-二甲基-1,6-己二胺 以 二氯甲烷 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  Syntheses and Mesomorphic Properties of Gold(I)−Carbene Complexes

  摘要：

  The liquid-crystalline gold(I)-carbene complexes ClAu=C(YCmH2m+1)(NHC6H4CO2C6H4OCnH2n+1), Y = O and NH, have been prepared by reactions of gold(I)-isonitrile complexes [ClAu{CNC6H4CO2C6H4OCnH2n+1}] with alcohols and amines, respectively. The gold(I)-(alkoxy)(amino)carbene complexes show stable enantiotropic smectic A phases over the range of around 15 degrees C. The partial double-bond character of the C-N bond in the carbene complex gives rise to two geometrical isomers (E:Z = ca. 3:1). Their molecular structures were spectroscopically characterized, and the E-isomer was confirmed by an X-ray structural analysis. The phase behaviors of E- and Z-isomers which were isolated by repeated recrystallization from CHCl3/Et(2)O or CH2Cl2/C6H14 were examined. In the gold(I)-diaminocarbene complexes, a novel dinuclear gold-carbene complex, [ClAu{C(NHC6H4CO2C6H4OCnH2n+1)}](NCH3CmH2mNCH3)[ClAu{C(NHC6H4CO2C6H4OCnH2n+1)}], was synthesized by the reaction with a secondary diamine. This dinuclear complex generated a smectic mesophase although it decomposed at temperatures below its clearing temperature.

  DOI：

  10.1021/om9606202