[Au2Cl2(1,3-bis(phenylthio)propane)] | 1020186-52-0

• 英文名称: [Au2Cl2(1,3-bis(phenylthio)propane)]
• CAS: 1020186-52-0
• 化学式: C₁₅H₁₆Au₂Cl₂S₂
• 分子量: 725.263
• InChiKey: SFEJARHUIRXSLB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四氯金酸水合物 、 1,3-双(苯基硫代)丙烷 以 乙醇 为溶剂， 以68%的产率得到[Au2Cl2(1,3-bis(phenylthio)propane)]
  参考文献：
  名称：

  Gold(I)−Dithioether Supramolecular Polymers: Synthesis, Characterization, and Luminescence

  摘要：

  A series of discrete compounds and supramolecular polymers were synthesized by self-assembly of dithioether building blocks and HAuCl4 center dot 3H(2)O. In complexes 1 {[AuL1-MeCl], where L1-me is bis(methylthio)methane} and 2 {[Au-2 L2-PhCl2], where L2-Ph is 1,2-bis(phenylthio)ethane}, adjacent units are connected via aurophilic interactions. Complex 1, a one-dimensional (1D) supramolecular polymer, and complex 2, a two-dimensional supramolecular network, both feature nearly linear [Au-Au-](infinity) chains. Complexes 4a, 4b, and 4c, all of which contain 1,3-bis(phenylthio)propane (L3-Ph), are polymorphs having the composition [AU(2)L(3-Ph)Cl(2)]. Complex 3 {[Au2L1-PhCl2], where L1-Ph is bis(phenylthio)methane}and complexes 4a and 4b consist of nearly identical 1D supramolecular polymers formed through Au-Au interactions. The third polymorph, 4c, is a molecular complex, as it does not have metal-metal interactions. Complex 5 {[Au2L4-PhCl](2), where L4-Ph is 1,4-bis(phenylthio)butane} is also molecular. UV-vis spectra showed that the absorption bands of these complexes are allowed ligand-centered transitions between 230 and 260 nm. Complexes 1, 2, and 6 {[AuL3-MeCl], where L3-Me is 1,3-bis(methylthio)propane} exhibited solid-state luminescence at 5 K with vibronic progressions and band maxima at approximately 570 nm. It is suggested that complex 6 contains [Au-Au-](infinity) chains.

  DOI：

  10.1021/ic701275k