(μ-sodium)di[(2-(2'-oxyphenyl)-1,3-bis[4-(2-oxyphenyl)-3-azabut-3-enyl]-1,3-imidazolidine)bis(azido)dicopper(II)] perchlorate dihydrate | 886982-25-8

• 英文名称: (μ-sodium)di[(2-(2'-oxyphenyl)-1,3-bis[4-(2-oxyphenyl)-3-azabut-3-enyl]-1,3-imidazolidine)bis(azido)dicopper(II)] perchlorate dihydrate
• CAS: 886982-25-8
• 化学式: C₅₄H₅₄Cu₄N₁₄NaO₆*ClO₄*2H₂O
• 分子量: 1407.77
• InChiKey: RZSBRROLHMALNY-MYVHNJEISA-G

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  sodium azide 、 (μ-chloro)di[(2-(2'-oxyphenyl)-1,3-bis[4-(2-oxyphenyl)-3-azabut-3-enyl]-1,3-imidazolidine)dicopper(II)] perchlorate dodecahydrate 以 甲醇 、 乙腈 为溶剂， 生成 (μ-sodium)di[(2-(2'-oxyphenyl)-1,3-bis[4-(2-oxyphenyl)-3-azabut-3-enyl]-1,3-imidazolidine)bis(azido)dicopper(II)] perchlorate dihydrate
  参考文献：
  名称：

  [Cu ^II ₄ ] Clusters From the Self‐Assembly of Two Imidazolidinyl 2‐Phenolate‐Bridged [Cu ^II ₂ ] Units: The Role of the Chloride Bridge

  摘要：

  AbstractA new family of tetracopper clusters [Cu4(μ4‐X)L2]ClO4·nH2O (1a–c) [X = Cl, Br, I; n = 12, 2, 2; H3L = 2‐(2′‐hydroxyphenyl)‐1,3‐bis[4‐(2‐hydroxyphenyl)‐3‐azabut‐3‐enyl]‐1,3‐imidazolidine] have been synthesised and characterised. The X‐ray crystal structure of 1a reveals that the template action of the spherical Cl– anion (μ4‐Cl–), which features a unique rectangular planar bridging mode, is responsible for the self‐assembly of two [Cu2L]+ units in complex 1a. In this family of complexes the spherical halides serve as templates to assemble the dimeric unit into tetrameric complexes, which gives an insight into the role of the halide bridge in tetranuclear complex formation. The capacity of this bridge to mediate magnetic coupling has been examined by bulk magnetic measurements for complex 1a. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

  DOI：

  10.1002/ejic.200600917

文献信息

• [NaCu^II₄] Cluster from Alkali Template Assembly of Two Asymmetric End-On Azido-Bridged [Cu^II₂] Units
  作者：Prasant Kumar Nanda、Guillem Aromí、Debashis Ray

  DOI：10.1021/ic052209p

  日期：2006.4.17

  The cluster [NaCu4L2(N3)2](ClO4) [1; H3L is 2-(2'-hydroxyphenyl)-1,3-bis[3'-aza-4'-(2''-hydroxyphenyl)prop-4'-en-1'-yl]-1,3-i midazolidine] has been synthesized and structurally characterized. Complex 1 is formed by the template assembly of two [Cu2L(N3)] neutral fragments through their weak oxophilic interactions with a central Na+ cation as observed in metallacrowns. The cluster exhibits a combination

  簇[NaCu4L2（N3）2]（ClO4）[1；H3L是2-（2'-羟基苯基）-1,3-双[3'-氮杂-4'-（2''-羟基苯基）prop-4'-en-1'-基] -1,3-i咪唑烷]已合成并进行了结构表征。配合物1是通过两个[Cu2L（N3）]中性片段的模板组装而形成的，这是通过它们与中央Na +阳离子之间弱的亲氧相互作用而实现的，如在金属漆中所观察到的那样。该团簇表现出铁磁性和反铁磁性相互作用的组合。[Cu（II）2]单元内的铜离子的末端N3桥联促进了S = 1磁性亚基的稳定化，这些亚基通过反铁磁耦合相互抵消，该反铁磁耦合由O ... Na + ... O桥介导。