| 1374858-11-3

• CAS: 1374858-11-3
• 化学式: C₃₆H₃₇Cl₂FePRu
• 分子量: 728.487
• InChiKey: FQLAKHKMJZEBPL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichloro(p-cymene)ruthenium(II) dimer 、 (η5-C5H5)Fe(η5-C5H4)CCP(o-tolyl)2 以 二氯甲烷 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  (Ethynylferrocenyl)phosphine ruthenium complexes in catalytic β-oxopropyl benzoate formation

  摘要：

  The synthesis of a series of (ethynylferrocenyl)phosphino ruthenium compounds of type (FcC C)R2P(RuCl2(eta(6)-p-cymene)) (3a, R = C6H5; 3b, R = 2-CH3C6H4; 3c, R = (C4H3O)-C-c; 3d, R = t-Bu; 3e, R = (C6H11)-C-c; p-cymene = 1-(C3H7)-C-i-4-CH3-C6H4; Fc = Fe(eta(5)-C5H4)(eta(5)-C5H5)) and (RuCl2(eta(6)-p-cymene))(FcC C)P(C CPPh2(RuCl2(eta(6)-p-cymene)))(2) (10) resulting from the addition of ferrocenylphosphines P(C CFc)R-2 (1a-1e) or P(C CFc)(C CPPh2)(2) (9) to [RuCl2(eta(6)-p-cymene)](2) (2) is described. The structures of 3b, 3c and 10 in the solid state are reported confirming the expected tetrahedral coordination sphere about the phosphorus atom as well as the "piano-stool" arrangement about the ruthenium atom(s). Ruthenium complexes 3 and 10 are catalytically active under mild conditions in the alkyne-to-carboxylic acid coupling as it was shown for the reaction of propargyl alcohol with benzoic acid. A comparison with literature known [RuCl2(PR3)(eta(6)-p-cymene)] catalysts is presented. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.02.025