chloromethyl-[(2-pyridyl-2-furylmethyl)imine]palladium(II) | 1333887-45-8

• 英文名称: chloromethyl-[(2-pyridyl-2-furylmethyl)imine]palladium(II)
• CAS: 1333887-45-8
• 化学式: C₁₂H₁₃ClN₂OPd
• 分子量: 343.121
• InChiKey: GYSLNSARNHFWCZ-ORBBEKEHSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  chloromethyl-[(2-pyridyl-2-furylmethyl)imine]palladium(II) 、 四(3,5-二(三氟甲基)苯基)硼酸钠 以 氘代氯仿 为溶剂， 生成 methyl-[(2-pyridyl-2-furylmethyl)imine]palladium(II) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
  参考文献：
  名称：

  Novel hemi-labile pyridyl-imine palladium complexes: Synthesis, molecular structures and reactions with ethylene

  摘要：

  Ligands (2-pyridyl-2-furylmethyl)imine, (L1), (2-pyridyl-2-thiophenemethyl)imine (12), and (2-pyridyl-2-thiopheneethyl)imine (L3) were synthesized by condensation reactions and obtained in good yields. Reactions of L1-L3 with either [PdClMe(cod)] or [PdCl2(cod)] gave the corresponding monometallic palladium(II) complexes 1-5 in very good yields. Molecular structures of complexes 1,4 and 5 indicated that the ligands are bidentate and coordinate to the palladium metal through the imine and pyridine nitrogen atoms. When complexes 3-5 were treated with NaBAr4, cationic species, 3a, 4a, and 5a were produced which catalyzed polymerization of ethylene though with very low activities. H-1 NMR spectroscopy studies showed that these cationic species were very stable in solution. DFT calculations showed high ethylene coordination barriers to the cationic species 3a, 4a and 5a. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.07.004
• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 N-(furan-2-ylmethyl)-1-(pyridin-2-yl)methylimine 以 乙醚 、 二氯甲烷 为溶剂， 以98%的产率得到chloromethyl-[(2-pyridyl-2-furylmethyl)imine]palladium(II)
  参考文献：
  名称：

  Novel hemi-labile pyridyl-imine palladium complexes: Synthesis, molecular structures and reactions with ethylene

  摘要：

  Ligands (2-pyridyl-2-furylmethyl)imine, (L1), (2-pyridyl-2-thiophenemethyl)imine (12), and (2-pyridyl-2-thiopheneethyl)imine (L3) were synthesized by condensation reactions and obtained in good yields. Reactions of L1-L3 with either [PdClMe(cod)] or [PdCl2(cod)] gave the corresponding monometallic palladium(II) complexes 1-5 in very good yields. Molecular structures of complexes 1,4 and 5 indicated that the ligands are bidentate and coordinate to the palladium metal through the imine and pyridine nitrogen atoms. When complexes 3-5 were treated with NaBAr4, cationic species, 3a, 4a, and 5a were produced which catalyzed polymerization of ethylene though with very low activities. H-1 NMR spectroscopy studies showed that these cationic species were very stable in solution. DFT calculations showed high ethylene coordination barriers to the cationic species 3a, 4a and 5a. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.07.004