dimethyl 1',1'-ureylenedi(1-ferrocenecarboxylate) | 443983-83-3

• 英文名称: dimethyl 1',1'-ureylenedi(1-ferrocenecarboxylate)
• CAS: 443983-83-3
• 化学式: C₂₅H₂₄Fe₂N₂O₅
• 分子量: 544.17
• InChiKey: VVSRBHAFUZEGTB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  methyl 1'-azidocarbonylferrocene-1-carboxylate 、 叔丁醇 以 叔丁醇 为溶剂， 以9%的产率得到dimethyl 1',1'-ureylenedi(1-ferrocenecarboxylate)
  参考文献：
  名称：

  Electronic communication through the ureylene bridge: spectroscopy, structure and electrochemistry of dimethyl 1′,1′-ureylenedi(1-ferrocenecarboxylate)

  摘要：

  Dimethyl 1',1'-ureylenedi(1-ferrocenecarboxylate) (1) formed during the synthesis of 1-amino, 1'-ferrocenecarboxylic acid shows virtual molecular centrosymmetry. Electronic coupling between the two Fc groups through the ureylene bridge results in both Fc groups being individually oxidizable (DeltaE(1/2) much greater than 0.14 V). The possible existence of intermolecular electronic communication has discussed. The oxidation was followed by spectroelectrochernistry. The separation between the two halfwave potentials DeltaE(1/2) = 137 +/- 5 mV and the comproportionation constant K-c = 207. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.04.016