| 215796-48-8

• CAS: 215796-48-8
• 化学式: C₁₇H₁₀Mo₂O₇OsS
• 分子量: 740.408
• InChiKey: MWUCUMNBTMRPBM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  十二羰基三锇 、 cyclo-μ3-Sulfido-(tricarbonyleisen)bis[dicarbonyl(η-cyclopentadienyl)molybdaen](2Fe-Mo,Mo-Mo) 以 甲苯 为溶剂， 以20%的产率得到
  参考文献：
  名称：

  Synthesis, characterisation and nonlinear optical properties of tetrahedral clusters Cp2Mo2ME(CO)7, (M=Fe, Ru, Os; E=S, Se)

  摘要：

  A set of new chalcogen-bridged mixed metal clusters, Cp2Mo2M(mu(3)-E)(CO)(7), (M = Fe, Ru, Os; E = S, Se) have been synthesised and characterised by IR and NMR spectroscopy, and structures of Cp2Mo2Ru(mu(3)-Se)(CO)(7) and Cp2Mo2Os(mu(3)-Se)(CO)(7) have been established by single crystal X-ray diffraction methods. The nonlinear optical properties of these clusters were investigated through the Z-scan technique, using 35 ps laser pulses at 532 nm. We report large refractive third order nonlinearity for these clusters indicating their promise for optical limiting applications. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00810-9