(η5-cyclopentadienyl)Fe(CO)2(CH2Si(Me)(n-Bu)Cl) | 669048-60-6

• 英文名称: (η5-cyclopentadienyl)Fe(CO)2(CH2Si(Me)(n-Bu)Cl)
• CAS: 669048-60-6
• 化学式: C₁₃H₁₉ClFeO₂Si
• 分子量: 326.678
• InChiKey: CNAZOOOXMUWQAB-XWCOYVICSA-N

反应信息

• 作为反应物：
  描述：

  (η5-cyclopentadienyl)Fe(CO)2(CH2Si(Me)(n-Bu)Cl) 在 lithium diisopropylamide 作用下， 以 not given 为溶剂， 生成 Fe(CO)2(η5-C5H4Si(Me)(n-Bu)CH2)
  参考文献：
  名称：

  Isolation and Ring-Opening of New 1-Sila-3-metallacyclobutanes (η⁵-C₅H₄Fe)(CO)₂CH₂SiR₂ Leading to A New Class of Organometallic Polymer

  摘要：

  Treatment of FpCH2SiR2Cl [Fp = (eta5-C5H5)Fe(CO)2] with lithium diisopropylamide leads to the formation of new metallacycle complexes. When R2 = Me2 and MenBu, these ring-open to form a new class of organometallic polymer. When R2 = nBu2, the metallacycle resists ring-opening and may be structurally characterized as the Ph3P-substituted species.

  DOI：

  10.1021/ja030559+
• 作为产物：
  描述：

  (η5-cyclopentadienyl)Fe(CO)2(Si(Me)(n-Bu)CH2Cl) 以 苯 为溶剂， 以99%的产率得到(η5-cyclopentadienyl)Fe(CO)2(CH2Si(Me)(n-Bu)Cl)
  参考文献：
  名称：

  Isolation and Ring-Opening of New 1-Sila-3-metallacyclobutanes (η⁵-C₅H₄Fe)(CO)₂CH₂SiR₂ Leading to A New Class of Organometallic Polymer

  摘要：

  Treatment of FpCH2SiR2Cl [Fp = (eta5-C5H5)Fe(CO)2] with lithium diisopropylamide leads to the formation of new metallacycle complexes. When R2 = Me2 and MenBu, these ring-open to form a new class of organometallic polymer. When R2 = nBu2, the metallacycle resists ring-opening and may be structurally characterized as the Ph3P-substituted species.

  DOI：

  10.1021/ja030559+