(η4-7-methoxycarbonyl-2-p-toluenesulfonyl-7-azanorbornadiene)Mo(CO)4 | 851663-03-1

• 英文名称: (η4-7-methoxycarbonyl-2-p-toluenesulfonyl-7-azanorbornadiene)Mo(CO)4
• CAS: 851663-03-1
• 化学式: C₁₉H₁₅MoNO₈S
• 分子量: 513.336
• InChiKey: LIXDOFIPHPXUMI-ZIMBGSPVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二氯甲烷 、 7-methoxycarbonyl-2-p-toluenesulfonyl-7-azanorbornadiene 、 乙腈 、 molybdenum hexacarbonyl 在 (CH₃)3NO 作用下， 以 二氯甲烷 为溶剂， 以12.6%的产率得到(η4-7-methoxycarbonyl-2-p-toluenesulfonyl-7-azanorbornadiene)Mo(CO)4
  参考文献：
  名称：

  Reaction of Mo(CO)4(NCCH3)2 and 7-aza-2-Tosylnorbornadiene

  摘要：

  Reaction of Mo(CO)(4)(NCCH3)(2) and 7-aza-2-tosylnorbornadiene (7-azaNBD) yielded five air-stable Mo complexes. One is Mo(CO)(4)(eta(4)-7-azaNBD), in which the molybdenum atom is chelated by the two pi-bonds of 7-azaNBD. The other four are isomers of Mo(CO)(2)( eta(2)-7-azaNBD)(2), in which the molybdenum atoms are chelated by the nitrogen atom and one of the two double bonds of 7-azaNBD. In one pair of the isomers, the metal binds to C(2)=C(3) of both 7-azaNBD ligands; whereas in the other pair of isomers the metal binds to C(2)=C(3) of one 7-azaNBD ligand and C(5)=C(6) of another ligand. All structures were fully characterized by NMR spectra. A single crystal of compound 4 was analyzed by X-ray diffraction analysis, which was found to be monoclinic with a = 8.4199 b = 23.984, c = 16.395 angstrom, and beta = 99.99 degrees. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.12.058