tetraphenylphosphonium tetra(benzeneselenolato)indium(III) | 210635-43-1

• 英文名称: tetraphenylphosphonium tetra(benzeneselenolato)indium(III)
• CAS: 210635-43-1
• 化学式: C₂₄H₂₀InSe₄*C₂₄H₂₀P
• 分子量: 1078.48
• InChiKey: IMPCCEYATDDFSQ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二苯基二硒醚 、 氯化铟 、 四苯基氯化膦 在 NaBH₄ 作用下， 以 乙醇 为溶剂， 以46%的产率得到tetraphenylphosphonium tetra(benzeneselenolato)indium(III)
  参考文献：
  名称：

  The syntheses and crystal structures of [PPh4] [In (SePh) 4] and [PPh4] [In(SePh)3(SeH)]

  摘要：

  The reaction of InCl3 with NaSePh in ethanol followed by addition of PPh4Cl affords tetraphenylphosphonium tetra (benzeneselenolato)indium(III), [PPh4][In(SePh)(4)] (1). Reaction of the [In(SePh4)](-) reaction mixture with NaBH4 and elemental sulfur followed by the addition of PPh4Cl yields tetraphenylphosphonium tri(benzeneselenolato)(hydroselenido)indium(III), [PPh4][In(SePh)(3)(SeH)] (2). The structures of 1 and 2, as determined from single-crystal X-ray data, feature well-separated cations;and anions with the In(III) centers of the anions tetrahedrally coordinated to four [SePh](-) ligands or three [SePh](-) ligands and one [SeH](-) ligand, respectively. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00439-7