GeCl4*2,2'-bipyridine | 18726-06-2

• 英文名称: GeCl4*2,2'-bipyridine
• 英文别名: germanium tetrachloride*2,2'-bipyridyl；(2,2'-dipyridyl)tetrachlorogermanium；GeCl₄*2,2'-bipyridine；[GeCl4(2,2'-bipyridyl)]；GeCl4(2,2'-bipyridine)；[GeCl4(2,2'-bipy)]；GeCl4(bipy)
• CAS: 18726-06-2
• 化学式: C₁₀H₈Cl₄GeN₂
• 分子量: 370.589
• InChiKey: OBZOAQYMMBSZAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  GeCl4*2,2'-bipyridine 在 potassium thioacyanate 作用下， 以 氘代丙酮 为溶剂， 生成
  参考文献：
  名称：

  73Ge NMR of hexacoordinate organogermanium compounds

  摘要：

  DOI：

  10.1016/0022-328x(89)87092-5
• 作为产物：
  描述：

  四氯化锗 在 2,2'-联吡啶 作用下， 以 neat (no solvent) 为溶剂， 生成 GeCl4*2,2'-bipyridine
  参考文献：
  名称：

  Sevast'yanova, T. N.; Korobkina, E. V.; Suvorov, A. V., Russian Journal of Inorganic Chemistry, 1988, vol. 33, p. 1670 - 1673

  摘要：

  DOI：

文献信息

• Synthesis, Spectroscopic and Structural Systematics of Complexes of Germanium(IV) Halides (GeX ₄ , X = F, Cl, Br or I) with Mono‐, Bi‐ and Tri‐Dentate and Macrocyclic Nitrogen Donor Ligands
  作者：Fei Cheng、Martin F. Davis、Andrew L. Hector、William Levason、Gillian Reid、Michael Webster、Wenjian Zhang

  DOI：10.1002/ejic.200700727

  日期：2007.11

  six-coordinate adducts cis-[GeX4(L-L)] (L-L = 2,2-bipyridyl, 1,10-phenanthroline, or Me2NCH2CH2NMe2, X = F, Cl or Br) have been synthesised and characterised by IR and VT 1H and 19F1H} NMR spectroscopy. X-ray crystal structures reveal distorted octahedral geometries and the trends in d(Ge-N) with halide are interpreted in terms of varying Lewis acidity within the series. The trans-[GeX4(py)2] were similarly

  六配位加合物 cis-[GeX4(LL)] (LL = 2,2-bipyridyl, 1,10-phenanthroline, or Me2NCH2CH2NMe2, X = F, Cl 或 Br) 已经合成并通过 IR 和 VT 1H 表征19F1H}核磁共振谱。X 射线晶体结构揭示了扭曲的八面体几何形状，并且 d(Ge-N) 与卤化物的趋势是根据系列中不同的路易斯酸度来解释的。反式-[GeX4(py)2] 的特征相似。相比之下，GeI4 不会形成类似的加合物，尽管它似乎与一些配体共结晶，并且 ·(1,10-phenH)3·I3 的结构包含菲咯啉阳离子、碘化物阴离子和四面体 分子被报道。多齿氮供体配体，包括环丙烷（1,4,8,11-四氮杂环十四烷）和 Me4-环丙烷（1,4,8,11-四甲基-1,4,8，11-四氮杂环十四烷）与 [GeF4(MeCN)2] 反应形成不溶性化合物
• Anatsko; Sevast'yanova; Suvorov, Russian Journal of General Chemistry, 1999, vol. 69, # 8, p. 1262 - 1265
  作者：Anatsko、Sevast'yanova、Suvorov、Kondrat'ev

  DOI：——

  日期：——
• Ge(IV)–citrate complex formation: synthesis and structural characterisation of GeCl4(bipy) and GeCl(bipy)(Hcit) (bipy=2,2′-bipyridine, H4cit=citric acid)
  作者：Gerald R. Willey、Usha Somasunderam、Damian R. Aris、William Errington

  DOI：10.1016/s0020-1693(01)00358-9

  日期：2001.4

  The adduct [GeCl4(bipy)] (I), obtained by direct treatment of the parent halide with 2,2'-bipyridine (bipy), reacts with citric acid (H(4)cit) in acetonitrile solution to provide the chelate derivative [GeCl(bipy)(Hcit)] (II). The structures of compounds I and II have been determined by single crystal X-ray diffraction. For I the central germanium shows octahedral geometry with two mutually cis-chlorine atoms, Ge-Cl (mean) 2.244(1) Angstrom, and the bidentate ligand, Ge-N (mean) 2.065(4) Angstrom occupying equatorial positions and two mutually tuans-chlorine atoms, Ge-Cl (mean) 2.267(1) Angstrom in axial locations. For II the citrate ligand is terdentate and bound to the central germanium via its hydroxyl, alpha -carboxylate and one of the beta -carboxylate groups in a fac-octahedral arrangement. Ge-O-hydroxyl 1.800(3) Angstrom, Ge-O-carboxylate (mean) 1.904(3) Angstrom, Ge-Cl 2.209(1) Angstrom, Ge-N (mean) 2.012(3) Angstrom. The uncoordinated P-carboxylate group remains intact as a 'dangling arm'. The structure also contains poorly defined and disordered acetonitrile (solvent) molecules trapped in the lattice. (C) 2001 Elsevier Science B.V. All rights reserved.