[Zn(dap)2Cl2] | 693252-40-3

• 英文名称: [Zn(dap)2Cl2]
• 英文别名: [Zn(2,3-diaminopyridine)2Cl2]
• CAS: 693252-40-3
• 化学式: C₁₀H₁₄Cl₂N₆Zn
• 分子量: 354.557
• InChiKey: YTCGUHAAHCNSKS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,3-二氨基吡啶 、 zinc(II) chloride 以 甲醇 、 乙醚 为溶剂， 以66%的产率得到[Zn(dap)2Cl2]
  参考文献：
  名称：

  Extended structures based on hydrogen bonding and π–π interactions: synthesis and characterization of two zinc complexes: [Zn(dap)Cl2] and [Zn(dap)2Cl2]

  摘要：

  Two new Zn(II) complexes, [Zn(dap)Cl-2] (1) and [Zn(dap)(2)Cl-2] (2) (dap stands for 2,3-diaminopyridine), were prepared and spectroscopically and crystallographically characterized. In both compounds, the zinc(II) atom has a pseudo-tetrahedral ZnN2Cl2 coordination environment. Compound I adopts a three-dimensional structure built up from [Zn(dap)Cl-2](n) zig-zag chains, which are linked by N-(HCl)-Cl-... hydrogen bonds. In compound 2 the dap is monodentate coordinating via the pyridine nitrogen the mononuclear tetrahedral [Zn(dap),Cl,] units are linked into two-dimensional sheets through extensive N-(HCl)-Cl-... hydrogen bonding. Inter-sheet pi-pi interactions connect them into a three-dimensional network. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.11.035