[(η²-cyclooctene)(η⁴-2,3-dimethylbuta-1,3-diene)Rh(μ-Cl)]₂ | 1449498-26-3

• 英文名称: [(η²-cyclooctene)(η⁴-2,3-dimethylbuta-1,3-diene)Rh(μ-Cl)]₂
• 英文别名: [(η²-C₈H₁₄)(η⁴-2,3-dimethylbuta-1,3-diene)Rh(μ-Cl)]₂
• CAS: 1449498-26-3
• 化学式: C₂₈H₄₈Cl₂Rh₂
• 分子量: 661.406
• InChiKey: QLMRXTMSSBSZTP-BJTMLYKVSA-L

反应信息

• 作为反应物：
  描述：

  、 [(η²-cyclooctene)(η⁴-2,3-dimethylbuta-1,3-diene)Rh(μ-Cl)]₂ 以 苯 为溶剂， 反应 2.0h， 以53%的产率得到
  参考文献：
  名称：

  Mixed-ligand di-µ-chloro-bridged Rhodium Dimers as Key Intermediates in the Synthesis of Acyclic (p-allyl)-closo-rhodacarboranes

  摘要：

  The mixed-ligand di-mu-chloro-bridged rhodium dimers [(eta(2)-C8H14)(eta(4)-2-methylbuta-1,3-diene)Rh(mu-Cl)](2) and [eta(2)-C8H14)(eta(4)-2,3-dimethylbuta-1,3-diene)Rh(mu-Cl)](2) were synthesized and characterized. These compounds are key precursors in the preparative synthesis of the acyclic (pi-allyl)-closo-rhodacarborane complexes [3- (pi-(R ''-allyl)}-1-R-2-R'-closo-3,1,2-RhC2B9H9], which were obtained earlier via the one-pot metallation of the K+ salts of the [7-R-8-R'-nido-7,8-C2B9H10](-) anions with [(eta(2)-C8H14)(4)Rh-2(mu-Cl)(2)] in the presence of substituted buta-1,3-diene ligands.

  DOI：

  10.1016/j.mencom.2013.07.004
• 作为产物：
  描述：

  di-μ-chloro-bis[bis(cyclo-octene)rhodium] 、 2,3-二甲基-1,3-丁二烯 以 正己烷 为溶剂， 反应 1.0h， 生成 [(η²-cyclooctene)(η⁴-2,3-dimethylbuta-1,3-diene)Rh(μ-Cl)]₂
  参考文献：
  名称：

  Mixed-ligand di-µ-chloro-bridged Rhodium Dimers as Key Intermediates in the Synthesis of Acyclic (p-allyl)-closo-rhodacarboranes

  摘要：

  The mixed-ligand di-mu-chloro-bridged rhodium dimers [(eta(2)-C8H14)(eta(4)-2-methylbuta-1,3-diene)Rh(mu-Cl)](2) and [eta(2)-C8H14)(eta(4)-2,3-dimethylbuta-1,3-diene)Rh(mu-Cl)](2) were synthesized and characterized. These compounds are key precursors in the preparative synthesis of the acyclic (pi-allyl)-closo-rhodacarborane complexes [3- (pi-(R ''-allyl)}-1-R-2-R'-closo-3,1,2-RhC2B9H9], which were obtained earlier via the one-pot metallation of the K+ salts of the [7-R-8-R'-nido-7,8-C2B9H10](-) anions with [(eta(2)-C8H14)(4)Rh-2(mu-Cl)(2)] in the presence of substituted buta-1,3-diene ligands.

  DOI：

  10.1016/j.mencom.2013.07.004