tetraethylammonium-1,2-bis(dimethylfluorostannyl)benzene fluoride | 219648-22-3

• 英文名称: tetraethylammonium-1,2-bis(dimethylfluorostannyl)benzene fluoride
• CAS: 219648-22-3
• 化学式: C₈H₂₀N*C₁₀H₁₆F₃Sn₂
• 分子量: 560.906
• InChiKey: QOBCDJCYXINMDA-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,2-bis(dimethylchlorostannyl)benzene 以 乙醚 、 二氯甲烷 、 水 为溶剂， 生成 tetraethylammonium-1,2-bis(dimethylfluorostannyl)benzene fluoride
  参考文献：
  名称：

  o-Bis(haloorganostannyl)benzenes As Powerful Bidentate Lewis Acids toward Halide Ions

  摘要：

  The synthesis of the o-phenylene-bridged ditin species o-C6H4(SnXMe2)(2) (2, X = Cl; 4, X = F) and o-C6H4(SnCl2Me)(2) (3) is reported and the crystal structures of [o-C6H4(SnClMe2)(2). Cl](-)[(Ph3N)(2)P](+) (5) and [o-C6H4(SnClMe2)(2). F](-)[K . C20H24O6](+) (7) are described. Variable-temperature Sn-119 and F-19 NMR studies indicate that 2 and 4 act as bidentate Lewis acids toward chloride and fluoride ions exclusively forming the stable anionic 1:1 complexes 5, 7, and [o-C6H4(SnFMe2)(2). F](-)[Et4N](+) (8). No formation of dianionic 1:2 adducts was observed even with excess of halide ions. The affinity of 2 toward fluoride is greater than toward chloride. Reaction of 2 with HMPA gives the neutral complex o-C6H4(SnClMe2)(2).(Me2N)(3)PO (10), the crystal structure of which is also described.

  DOI：

  10.1021/om980703d