| 157203-39-9

• CAS: 157203-39-9
• 化学式: C₃₂H₈₀As₂In₂Si₄
• 分子量: 956.812
• InChiKey: KSAJXTHXXVZZHI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Chlorobis(2,2-dimethylpropyl)indigane 、 以 氘代苯 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Characterization of Neopentyl Indium Compounds: X-ray Crystal Structures of [(Me3CCH2)2InAs(SiMe3)2]2 and (Me3CCH2)2InAs(SiMe3)2In(CH2CMe3)2Cl

  摘要：

  The 1:1 and 2:1 mole ratio reactions of(Me(3)CCH(2))(2)InCl with As(SiMe(3))(3) yield the dimeric and mixed-bridging compounds [(Me(3)CCH(2))(2)InAs(SiMe(3))(2)](2) (1) and (Me(3)CCH(2))(2)InAs(SiMe(3))(2)In(CH(2)CMe(3))(2)Cl (2), respectively. 1 and 2 were characterized by melting point, H-1 and C-13 NMR spectra, partial elemental analyses (C and H), and single-crystal X-ray analyses. Dimer 1 crystallizes in the monoclinic system, space group C2/m (C(2)h(3)), with a 19.789(2) Angstrom, b = 12.878(1) Angstrom, c 12.282(1) Angstrom, beta = 127.49(1)degrees, V = 2484(1) Angstrom(3), and Z = 2. Crystals of 2 belong to the monoclinic system, space group C2/c (C-2h(6)), With a = 20.191(2) Angstrom, b = 9.967(1) Angstrom, C = 19.758(2) Angstrom, beta = 99.67(1)degrees, V = 3920(1) Angstrom(3), and Z = 4. The facile interconversions of 1 and 2 are reported.

  DOI：

  10.1021/om00021a041
• 作为产物：
  描述：

  Chlorobis(2,2-dimethylpropyl)indigane 以 氘代苯 、 苯 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Characterization of Neopentyl Indium Compounds: X-ray Crystal Structures of [(Me3CCH2)2InAs(SiMe3)2]2 and (Me3CCH2)2InAs(SiMe3)2In(CH2CMe3)2Cl

  摘要：

  The 1:1 and 2:1 mole ratio reactions of(Me(3)CCH(2))(2)InCl with As(SiMe(3))(3) yield the dimeric and mixed-bridging compounds [(Me(3)CCH(2))(2)InAs(SiMe(3))(2)](2) (1) and (Me(3)CCH(2))(2)InAs(SiMe(3))(2)In(CH(2)CMe(3))(2)Cl (2), respectively. 1 and 2 were characterized by melting point, H-1 and C-13 NMR spectra, partial elemental analyses (C and H), and single-crystal X-ray analyses. Dimer 1 crystallizes in the monoclinic system, space group C2/m (C(2)h(3)), with a 19.789(2) Angstrom, b = 12.878(1) Angstrom, c 12.282(1) Angstrom, beta = 127.49(1)degrees, V = 2484(1) Angstrom(3), and Z = 2. Crystals of 2 belong to the monoclinic system, space group C2/c (C-2h(6)), With a = 20.191(2) Angstrom, b = 9.967(1) Angstrom, C = 19.758(2) Angstrom, beta = 99.67(1)degrees, V = 3920(1) Angstrom(3), and Z = 4. The facile interconversions of 1 and 2 are reported.

  DOI：

  10.1021/om00021a041