(tris(pyrazolyl)methanesulfonate(1-)-N,N,N)VCl2(N,N-dimethylformamide) | 1163298-90-5

• 英文名称: (tris(pyrazolyl)methanesulfonate(1-)-N,N,N)VCl2(N,N-dimethylformamide)
• CAS: 1163298-90-5
• 化学式: C₁₃H₁₆Cl₂N₇O₄SV
• 分子量: 488.228
• InChiKey: DKYNLIYBYNOQCM-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  (tris(pyrazolyl)methanesulfonate(1-))VCl2(N,N-dimethylformamide) 以 二氯甲烷-D2 为溶剂， 生成 (tris(pyrazolyl)methanesulfonate(1-)-N,N,O)VCl2(N,N-dimethylformamide) 、 (tris(pyrazolyl)methanesulfonate(1-)-N,N,N)VCl2(N,N-dimethylformamide)
  参考文献：
  名称：

  Synthesis, catalytic activity, phosphatase inhibition activity, and X-ray structural characterization of vanadium scorpionate complexes, (Tpms)VCl2(DMF) and (Tpms)VOCl(DMF)

  摘要：

  The complexes (Tpms)VCl2(DMF) (1), and (Tpms)VOCl(DMF) (2), have been synthesized and characterized. Complex 2 has also been structurally characterized via X-ray diffractometry. The vanadium(IV) center possesses a square pyramidal/distorted octahedral geometry with a facially coordinating Tpms ligand in a kappa(3)-N,N,O coordination mode. The complex is the first structurally characterized example of a vanadium(IV) complex with Tpms . Complex 2 shows catalytic activity towards oxidation of 3,5-di-tertbutyl catechol and also exhibits phosphatase inhibition characteristics on alkaline phosphatase. Tpms = trispyrazolylmethanesulfonate; DMF = N,N-dimethylformamide. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.12.004