| 1609253-70-4

• CAS: 1609253-70-4
• 化学式: C₁₅H₂₃Br₂CdN₅
• 分子量: 545.599
• InChiKey: MNMYJAJSYZPUHI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cadmium(II) bromide tetrahydrate 、 N-((1H-pyrazol-1-yl)methyl)-N-(cyclohexylmethyl)(1Hpyrazol-1-yl)methanamine 以 乙醇 为溶剂， 反应 12.0h， 生成
  参考文献：
  名称：

  Cadmium(II) complexes containing N′-substituted N,N-bispyrazolyl ligands: The formation of 4- and 5-coordinated monomers versus 6-coordinated dimer

  摘要：

  Novel Cd (II) bromide complexes [LaCdBr2], [LbCdBr2] and [LcCd(mu-Br)Br](2) have been synthesized and characterized. [LaCdBr2] and [LbCdBr2] were distorted tetrahedral and trigonal bipyramidal geometry around metal, respectively, depending on the coordination of the nitrogen atom of N '-substituted amine moiety and the cadmium center. However, [LcCd(mu-Br)Br](2) reveals a bromo-bridged 6-coordinated dimeric species. Specifically, the catalytic activity of [LbCdBr2] (1.13 x 10(5) g PMMA/mol Cd.h) in the polymerization of methyl methacrylate (MMA) in the presence of modified methylaluminoxane (MMAO) at 60 degrees C was higher than that of [LaCdBr2] (5.03 x 10(4) g PMMA/mol Cd.h) and reference complex [CdCl2] (3.53 x 10(4) g PMMA/mol Cd.h). (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2014.03.027