[Ni(II)Cl2(S-(1H-benzimidazol-2-yl)methyl dithiocarbamate)(H2O)]*H2O | 1134186-22-3

• 英文名称: [Ni(II)Cl2(S-(1H-benzimidazol-2-yl)methyl dithiocarbamate)(H2O)]*H2O
• CAS: 1134186-22-3
• 化学式: C₁₃H₁₉Cl₂N₃NiOS₂*H₂O
• 分子量: 445.057
• InChiKey: FBLSHONQHOMPNU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ni(II)Cl2(S-(1H-benzimidazol-2-yl)methyl dithiocarbamate)(H2O)]*H2O 以 neat (no solvent) 为溶剂， 生成 nickel(II) sulfide
  参考文献：
  名称：

  Synthesis and anti-fungicidal activity of some transition metal complexes with benzimidazole dithiocarbamate ligand

  摘要：

  Seven transition metal complexes of benzimidazole ligand (HL) are reported and characterized based on elemental analyses, IR. solid reflectance, magnetic moment, molar conductance and thermal analyses (TGA and DTA). From the obtained data, the complexes were proposed to have the general formulae [MX2(HL)(H2O)]center dot yH(2)O, where M = Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cr(III); X = Cl-, SO42- and y = 0-4. The molar conductance data revealed that all the metal chelates were non-electrolytes. From the magnetic and solid reflectance spectra, it was found that the geometrical structure of these complexes is octahedral. The thermal behaviour of these chelates showed that the hydrated complexes loss water molecules of hydration in the first step followed immediately by decomposition of the anions and ligand molecules in the subsequent steps. Fungicidal activity of the prepared complexes and free ligand was evaluated against three soil borne fungi. Data obtained showed the higher biological activity of the prepared complexes than the parent Schiff base ligand. Formulation of the most potent complex was carried out in the form of 25% WP. Fungicidal activity of the new formulation was evaluated and compared with the standard fungicide Pencycuron (Monceren 25% WP). In most cases, the new formulation possessed higher fungicidal activity than the standard fungicide under the laboratory conditions. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2008.10.051
• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 S-(1H-benzimidazol-2-yl)methyl N,N-diethyldithiocarbamate 以 乙醇 、 水 为溶剂， 以68%的产率得到[Ni(II)Cl2(S-(1H-benzimidazol-2-yl)methyl dithiocarbamate)(H2O)]*H2O
  参考文献：
  名称：

  Synthesis and anti-fungicidal activity of some transition metal complexes with benzimidazole dithiocarbamate ligand

  摘要：

  Seven transition metal complexes of benzimidazole ligand (HL) are reported and characterized based on elemental analyses, IR. solid reflectance, magnetic moment, molar conductance and thermal analyses (TGA and DTA). From the obtained data, the complexes were proposed to have the general formulae [MX2(HL)(H2O)]center dot yH(2)O, where M = Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cr(III); X = Cl-, SO42- and y = 0-4. The molar conductance data revealed that all the metal chelates were non-electrolytes. From the magnetic and solid reflectance spectra, it was found that the geometrical structure of these complexes is octahedral. The thermal behaviour of these chelates showed that the hydrated complexes loss water molecules of hydration in the first step followed immediately by decomposition of the anions and ligand molecules in the subsequent steps. Fungicidal activity of the prepared complexes and free ligand was evaluated against three soil borne fungi. Data obtained showed the higher biological activity of the prepared complexes than the parent Schiff base ligand. Formulation of the most potent complex was carried out in the form of 25% WP. Fungicidal activity of the new formulation was evaluated and compared with the standard fungicide Pencycuron (Monceren 25% WP). In most cases, the new formulation possessed higher fungicidal activity than the standard fungicide under the laboratory conditions. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2008.10.051