[Pd(κ2-C,N-4-MeC6H3N(Me)NO)(TMEDA)]PF6 | 1176131-65-9

• 英文名称: [Pd(κ2-C,N-4-MeC6H3N(Me)NO)(TMEDA)]PF6
• CAS: 1176131-65-9
• 化学式: C₁₄H₂₅N₄OPd*F₆P
• 分子量: 516.763
• InChiKey: FNUWBCGEIQMJAU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 四甲基乙二胺 、 [Pd(μO2CMe)(κ2-C,N-4-MeC6H3N(Me)NO)]2 以 甲醇 为溶剂， 以66%的产率得到[Pd(κ2-C,N-4-MeC6H3N(Me)NO)(TMEDA)]PF6
  参考文献：
  名称：

  Bridge cleavage reactions of cyclopalladated nitrosamines with thioamides and related compounds

  摘要：

  The palladacycle [Pd(mu-O2CMe){kappa C-2,N-4-MeC6H3N(Me)NO}](2) readily undergoes bridge cleavage reactions with a variety of compounds containing donor functionalities including thioamides, 8-hydroxyquinoline, thioureas, selenoureas, acetylacetone derivatives, dithiocarbamates, xanthates, as well as bidentate N-donors to afford either the monomeric, neutral Pd(II) complexes [Pd{kappa C-2,N-4-MeC6H3N(Me)NO}{L-L}] or the monocationic complexes [Pd{kappa C-2,N-4-MeC6H3N(Me)NO}(N-N)]PF6 in high yields. A series of 15 different complexes was prepared and fully characterised spectroscopically and, in some cases, by X-ray diffraction. It was also found that the dithiocarbamato complex undergoes a disproportionation reaction in solution to give the bis(cyclometallated) complex [Pd{kappa C-2,N-4-MeC6H3N(Me)NO}(2)] as well as the bis(dithiocarbamato) complex [Pd{kappa S-2-S2CNEt2}(2)]. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.03.026