dichloro([N,N'-bis(2-aminophenyl)diaminoglyoxime])nickel(II) | 381249-54-3

• 英文名称: dichloro([N,N'-bis(2-aminophenyl)diaminoglyoxime])nickel(II)
• CAS: 381249-54-3
• 化学式: C₁₄H₁₆Cl₂N₆NiO₂
• 分子量: 429.916
• InChiKey: HNPXSWKHFPEGEM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dichloroglyoxime 、 dichloro([N,N'-bis(2-aminophenyl)diaminoglyoxime])nickel(II) 在 Na₂CO₃ 作用下， 以 甲醇 、 二氯甲烷 、 水 为溶剂， 以66%的产率得到(dichloro-[5,6:11,12-dibenzo-2,3,8,9-tetra(hydroxyimino)1,4,7,10-tetraazacyclododecane])-nickel(II)
  参考文献：
  名称：

  TEMPLATE SYNTHESIS OF TWO NEW GLYOXIME DERIVATIVES. CHARACTERIZATION AND INVESTIGATION OF THEIR COMPLEXES WITH Ni(II), Cu(II), AND Co(II) METAL IONS

  摘要：

  Two novel oximes containing di- and tetraoxime groups, dichloro-[N,N'-bis(2-aminophenyl)diaminoglyoxime]nickel(II), [Ni(LH2)Cl-2], and {dichloro-[5,6:11,12-dibenzo-2,3,8,9-tetra(hydroxyimino)-1,4,7,10-tetraazacyelododecane]}- nickel(II), [Ni(LH4)Cl-2], have been synthesized by the template condensation reaction of dichloro-[N,N'-bis-(1,2-diaminobenzene)]nickel(II) with anti-dichloroglyoxime. Trinuclear complexes of [Ni(LH2)Cl-2] with Ni(II), Cu(II) and Co(II) have been synthesized. A polynuclear complex of [Ni(LH4)Cl-2] with Ni(II) has been prepared. The structures of these novel oxime compounds are proposed on the basis of the elemental analyses, IR and UV-Visible spectra and conductivity measurements. Conductivity measurements have shown that all complexes are non-electrolytes.

  DOI：

  10.1081/sim-100106853
• 作为产物：
  描述：

  dichloroglyoxime 、 Ni(o-phenylenediamine)2Cl2 在 Na₂CO₃ 作用下， 以 甲醇 、 水 为溶剂， 以60%的产率得到dichloro([N,N'-bis(2-aminophenyl)diaminoglyoxime])nickel(II)
  参考文献：
  名称：

  TEMPLATE SYNTHESIS OF TWO NEW GLYOXIME DERIVATIVES. CHARACTERIZATION AND INVESTIGATION OF THEIR COMPLEXES WITH Ni(II), Cu(II), AND Co(II) METAL IONS

  摘要：

  Two novel oximes containing di- and tetraoxime groups, dichloro-[N,N'-bis(2-aminophenyl)diaminoglyoxime]nickel(II), [Ni(LH2)Cl-2], and {dichloro-[5,6:11,12-dibenzo-2,3,8,9-tetra(hydroxyimino)-1,4,7,10-tetraazacyelododecane]}- nickel(II), [Ni(LH4)Cl-2], have been synthesized by the template condensation reaction of dichloro-[N,N'-bis-(1,2-diaminobenzene)]nickel(II) with anti-dichloroglyoxime. Trinuclear complexes of [Ni(LH2)Cl-2] with Ni(II), Cu(II) and Co(II) have been synthesized. A polynuclear complex of [Ni(LH4)Cl-2] with Ni(II) has been prepared. The structures of these novel oxime compounds are proposed on the basis of the elemental analyses, IR and UV-Visible spectra and conductivity measurements. Conductivity measurements have shown that all complexes are non-electrolytes.

  DOI：

  10.1081/sim-100106853