[Me4CpCH2CH2SMe]Co(Me)(NCCH3)B(3,5-(CF3)2C6H3)4 | 626254-12-4

• 英文名称: [Me4CpCH2CH2SMe]Co(Me)(NCCH3)B(3,5-(CF3)2C6H3)4
• CAS: 626254-12-4
• 化学式: C₁₅H₂₅CoNS*C₃₂H₁₂BF₂₄
• 分子量: 1173.65
• InChiKey: ROCYRBHVTDIWBZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  乙腈 、 tetrakis[3,5-bis(trifluoromethyl)phenyl]boric acid bis(diethyl ether) complex 、 [Me4CpCH2CH2SMe]CoMe2 以 二氯甲烷 为溶剂， 以99.4%的产率得到[Me4CpCH2CH2SMe]Co(Me)(NCCH3)B(3,5-(CF3)2C6H3)4
  参考文献：
  名称：

  Ethylene Polymerization Using Tetramethyl(2-methylthioethyl)cyclopentadienyl Complexes of Cobalt

  摘要：

  Tetramethyl(2-methylthioethyl)cyclopentadiene complexes of cobalt have been synthesized and tested in ethylene polymerization. In combination with MMAO-3A, tetramethyl(2-methylthioethyl)cyclopentadienylcobalt dilodide (4) was shown to polymerize ethylene to linear polyethylene with M(n)'s in the range of 5000-68 000. The activity of the catalyst is improved compared to the previously described catalysts containing the Cp*Co(+)(PR(3)) unit. Cationic (tetramethyl(2-methylthioethyl)cyclopentadienyl)methylcobalt nitrile complexes 8 were also shown to be competent ethylene polymerization catalysts, producing polyethylene with similar properties as observed with 4/MAIAO-3A.

  DOI：

  10.1021/om030414b