| 228580-12-9

• CAS: 228580-12-9
• 化学式: C₃₂H₈Co₄O₁₂
• 分子量: 820.381
• InChiKey: ZKOYJFXZXCSHAL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dicobalt octacarbonyl 、 [4.4]orthocyclopha-1,3,11,13-tetrayne 以 正己烷 、 二氯甲烷 为溶剂， 以39%的产率得到
  参考文献：
  名称：

  The synthesis and structural analysis of the bis-Co2(CO)6 adduct of the cyclic tetrayne C20H8

  摘要：

  The reaction of the cyclic tetrayne 2 with Co-2(CO)(8) at 25 degrees C has yielded the double addition product, C20H8[Co-2(CO)(6)](2), 3 in a 39% yield. Compound 3 was characterized by a single crystal X-ray diffraction analysis. The two Co-2(CO)(6) groupings have been added to two alkyne groups on opposite sides of the tetrayne ring in order to minimize steric interactions. The molecule is centrosymmetrical and the central C-12 ring is planar. The two Go-Co bonds are oriented perpendicular to the plane of the C-12 ring. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)01109-7