[(C5Me5)W(NO)Cl(η2-2,6-Me2C6H3N=C-n-C5H11)] | 1194440-66-8

• 英文名称: [(C5Me5)W(NO)Cl(η2-2,6-Me2C6H3N=C-n-C5H11)]
• CAS: 1194440-66-8
• 化学式: C₂₄H₃₅ClN₂OW
• 分子量: 586.858
• InChiKey: ANBVIEYRDNSVNH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(C5Me5)W(NO)(CH2CH=CHMe)(η2-2,6-Me2C6H3N=C-n-C5H11)] 、 B-氯-1,2-苯二酚硼烷 以 氘代苯 为溶剂， 生成 [(C5Me5)W(NO)Cl(η2-2,6-Me2C6H3N=C-n-C5H11)]
  参考文献：
  名称：

  Unprecedented Reactivity Initiated by Insertion of 2,6-Xylylisonitrile into the W−Alkyl Linkages of Cp*W(NO)(n-alkyl)(η³-CH₂CHCHMe) Complexes

  摘要：

  Treatment of the compounds Cp*W(NO)(R)(eta(3)- CH2CHCHMe) (R = n-C5H11, n-C7H15, n-C8H17) with 2,6-xylylisonitrile first produces the expected complexes bearing eta(2)-iminoacyl ligands arising from migratory insertion of the isonitrile into the tungsten-alkyl linkages, processes that result in the allyl ligands undergoing concomitant eta(3) -> eta(1) haptotropic shifts. These eta(1)-allyl complexes then undergo subsequent intramolecular nucleophilic attacks by their allyl groups on the nitrogen atoms of the eta(2)-iminoacyl ligands to form novel metallacyclic compounds that contain alpha-aminocarbene ligands.

  DOI：

  10.1021/om900739k