(2-ethoxyethanol)-aqua-beryllium phthalocyanine | 883967-96-2

• 英文名称: (2-ethoxyethanol)-aqua-beryllium phthalocyanine
• 英文别名: Be(phtalocyanine)(H2O)(2-ethoxyethanol)
• CAS: 883967-96-2
• 化学式: C₄H₁₀O₂*C₃₂H₁₈BeN₈O
• 分子量: 629.682
• InChiKey: ZSNOYQSECOLEEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (2-ethoxyethanol)-aqua-beryllium phthalocyanine 以 neat (no solvent) 为溶剂， 生成 beryllium phthalocyanine 、 水
  参考文献：
  名称：

  Synthesis, X-ray structures and characterization of beryllium phthalocyanine and (2-ethoxyethanol)-aqua-beryllium phthalocyanine

  摘要：

  Crystals of beryllium phthalocyanine (1) were obtained from the reaction of beryllium pieces with 1.2-dicyanobeilzene at 270 degrees C. In subsequent preparatory work the beryllium phtholocyanine was transformed into the monoaxially ligated compound (2-ethoxyethanol)aqua-beryllium phthalocyanine (11). The crystal structures of (1) and (11) were determined by single crystal X-ray diffraction. Based on thermogravimetric measurements, a conversion of the beryllium phthalocyanine into beryllium plithalocyanine monohydrate in wet air has been followed in detail. The beryllium phthalocyanine monohydrate and compound 11 loose the ligated water and 2-ethoxyethanol in the 150 degrees C region. The EPR spectra of the beryllium phthalocyanine complexes as exposed to air have been recorded and discussed. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.10.059
• 作为产物：
  描述：

  乙二醇乙醚 、 beryllium phthalocyanine 、 水 生成 (2-ethoxyethanol)-aqua-beryllium phthalocyanine
  参考文献：
  名称：

  Synthesis, X-ray structures and characterization of beryllium phthalocyanine and (2-ethoxyethanol)-aqua-beryllium phthalocyanine

  摘要：

  Crystals of beryllium phthalocyanine (1) were obtained from the reaction of beryllium pieces with 1.2-dicyanobeilzene at 270 degrees C. In subsequent preparatory work the beryllium phtholocyanine was transformed into the monoaxially ligated compound (2-ethoxyethanol)aqua-beryllium phthalocyanine (11). The crystal structures of (1) and (11) were determined by single crystal X-ray diffraction. Based on thermogravimetric measurements, a conversion of the beryllium phthalocyanine into beryllium plithalocyanine monohydrate in wet air has been followed in detail. The beryllium phthalocyanine monohydrate and compound 11 loose the ligated water and 2-ethoxyethanol in the 150 degrees C region. The EPR spectra of the beryllium phthalocyanine complexes as exposed to air have been recorded and discussed. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.10.059