trichloro(2-(2-benzoxazolyl)-6-(1-(2,6-diethylphenylimino)ethyl)pyridine-κN,N',N'')chromium(III) | 1160946-96-2

• 英文名称: trichloro(2-(2-benzoxazolyl)-6-(1-(2,6-diethylphenylimino)ethyl)pyridine-κN,N',N'')chromium(III)
• 英文别名: (E-2,6-diethyl-N-(1-(6-(benzoxazol-2-yl)pyridin-2-yl)ethylidene)benzenamine)CrCl3
• CAS: 1160946-96-2
• 化学式: C₂₄H₂₃Cl₃CrN₃O
• 分子量: 527.821
• InChiKey: HCUFEESILPBGSR-YUGFMNQLSA-K

反应信息

• 作为产物：
  描述：

  trichlorotritetrahydrofuran chromium(III) 、 2,6-diethyl-N-(1-(6-(benzo[d]oxazol-2-yl)pyridin-2-yl)ethylidene)benzenamine 以 二氯甲烷 为溶剂， 以95.4%的产率得到trichloro(2-(2-benzoxazolyl)-6-(1-(2,6-diethylphenylimino)ethyl)pyridine-κN,N',N'')chromium(III)
  参考文献：
  名称：

  Chromium(III) complexes bearing 2-benzoxazolyl-6-arylimino-pyridines: Synthesis and their ethylene reactivity

  摘要：

  A series of chromium(III) complexes bearing 2-benzoxazolyl-6-aryliminopyridines was synthesized and characterized by IR spectroscopic and CHN analysis. The X-ray crystallographic analysis of complex Cr3 revealed a distorted octahedral geometry. When activated by Et2AlCl, MAO or MMAO, these chromium complexes exhibited activities towards ethylene reactivity. High activities of ethylene oligomerization (up to 9.19 x 10(6) g mol(-1) (Cr) h(-1)) were observed in the catalytic system using MMAO as a cocatalyst, meanwhile good activities of ethylene polymerization were achieved (up to 5.20 x 10(5) g mol(-1) (Cr) h(-1)) by using MAO as a cocatalyst. Various reaction parameters were investigated in detail, and the steric and electronic effects of ligands were discussed. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.07.039