(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)(dichlorosilylene)V(CO)3(η5-C5H5) | 1316311-97-3

• 英文名称: (1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)(dichlorosilylene)V(CO)3(η5-C5H5)
• CAS: 1316311-97-3
• 化学式: C₃₅H₄₁Cl₂N₂O₃SiV
• 分子量: 687.655
• InChiKey: KYNDKMVKRXIGHQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetracarbonyl(η(5)-cyclopentadienyl)vanadium(I) 、 IPr*SiCl2 以 甲苯 为溶剂， 以73%的产率得到(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)(dichlorosilylene)V(CO)3(η5-C5H5)
  参考文献：
  名称：

  N-Heterocyclic Carbene Stabilized Dichlorosilylene Transition-Metal Complexes of V(I), Co(I), and Fe(0)

  摘要：

  Reactions of N-heterocyclic carbene stabilized dichlorosilylene IPr center dot SiCl2 (1) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) with (eta(5)-C5H5)V(CO)(4), (eta(5)-C5H5)Co(CO)(2), and Fe-2(CO)(9) afford dichlorosilylene complexes IPr center dot SiCl2 center dot V(CO)(3)(eta(5)-C5H5) (2), IPr center dot SiCl2 center dot Co(CO)-(eta(5)-C5H5) (3), and IPr center dot SiCl2 center dot Fe(CO)(4) (4), respectively. Complexes 2-4 are stable under an inert atmosphere, are soluble in common organic solvents, and have been characterized by elemental analysis and multinudear (H-1, C-13, and Si-29) NMR spectroscopy. Molecular structures of 2-4 have been determined by single crystal X-ray crystallographic studies and refined with nonspherical scattering factors.

  DOI：

  10.1021/ic201096c