[Cu(acetonitrile)][BPh4] | 1093866-10-4

• 英文名称: [Cu(acetonitrile)][BPh4]
• CAS: 1093866-10-4
• 化学式: C₂₆H₂₃BCuN
• 分子量: 423.832
• InChiKey: SQEAAPYHWJLJJF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2,2'-联吡啶 、 [Cu(acetonitrile)][BPh4] 以 二氯甲烷 为溶剂， 以55%的产率得到Cu(bpy)(BPh4)
  参考文献：
  名称：

  Strong Coordination of Tetraphenylborate Anion to Copper(I) Bipyridine and Phenanthroline-Based Complexes and Its Effect on Catalytic Activity in the Cyclopropanation of Styrene

  摘要：

  The synthesis, characterization, and cyclopropanation activity of tetrahedral copper(I) complexes with bipyridine- and phenanthroline-based ligands containing strongly coordinated tetraphenylborate anions are reported. Cu-I(bpy)(BPh4), Cu-I(phen)(BPh4), and Cu-I(3,4,7,8-Me(4)phen)(BPh4) complexes are the first examples in which the BPh4- counterion chelates a transition metal center in bidentate fashion through eta(2) pi interactions with two of its phenyl rings.

  DOI：

  10.1021/ic801783r
• 作为产物：
  描述：

  tetrakis(acetonitrile)copper(I) perchlorate 、 四苯硼钠 以 水 、 乙腈 为溶剂， 以0%的产率得到[Cu(acetonitrle)4]BPh4
  参考文献：
  名称：

  Strong Coordination of Tetraphenylborate Anion to Copper(I) Bipyridine and Phenanthroline-Based Complexes and Its Effect on Catalytic Activity in the Cyclopropanation of Styrene

  摘要：

  The synthesis, characterization, and cyclopropanation activity of tetrahedral copper(I) complexes with bipyridine- and phenanthroline-based ligands containing strongly coordinated tetraphenylborate anions are reported. Cu-I(bpy)(BPh4), Cu-I(phen)(BPh4), and Cu-I(3,4,7,8-Me(4)phen)(BPh4) complexes are the first examples in which the BPh4- counterion chelates a transition metal center in bidentate fashion through eta(2) pi interactions with two of its phenyl rings.

  DOI：

  10.1021/ic801783r