1-ferrocenylcarbonyl-2-ferrocenylcyclopentene | 67585-77-7

• 英文名称: 1-ferrocenylcarbonyl-2-ferrocenylcyclopentene
• CAS: 67585-77-7
• 化学式: C₂₆H₂₄Fe₂O
• 分子量: 464.17
• InChiKey: XAWANMZAVSCUHV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二茂铁 、 己二酰氯 在 三氯化铝 作用下， 以 二氯甲烷 为溶剂， 以28%的产率得到1,6-diferrocenylhexane-1,6-dione
  参考文献：
  名称：

  The synthesis, spectroscopic, electrochemical and X-ray diffraction characterization of novel bridged ferrocene precursors for use in self-assembled monolayers

  摘要：

  The synthesis of 1,6-diferrocenylhexane-1,6-dione (I), 1-ferrocenylcarbonyl-2-ferrocenylcyclopentene (II) and 1,6-diferrocenylhexane (III) is reported. All three compounds were characterized by H-1 NMR, C-13 NMR, and infra-red spectroscopy, mass spectrometry, cyclic voltammetry and chronoamperometry. Compounds I and III each exhibit a single two electron transfer, while compound (II) exhibits two single electron transfers. Compounds (I) and (II) were further studied by single crystal X-ray diffraction. In compound (I), both carbonyl groups are in plane with the adjacent ferrocenyl Cp ring. For compound (H) one of the ferrocenyl Cp rings is coplanar with the carbonyl group, the other with the double bond of the cyclopentene ring, but the C=O moiety and the double bond are basically perpendicular to each other. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.10.009