([2,4,6,8,9,10-hexamethyl-2,4,6,8,9,10-hexaaza-1,3,5,7-tetraphosphaadamantane]2(Cu(chloride))2).infin. | 1239193-66-8

• 英文名称: ([2,4,6,8,9,10-hexamethyl-2,4,6,8,9,10-hexaaza-1,3,5,7-tetraphosphaadamantane]2(Cu(chloride))2).infin.
• 英文别名: ([μ2-TPHMI]2(CuCl)2).infin.
• CAS: 1239193-66-8
• 化学式: C₁₂H₃₆Cl₂Cu₂N₁₂P₈
• 分子量: 794.286
• InChiKey: AGRUUIJUDUPVRR-KJQOLVGOSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,4,6,8,9,10-hexamethyl-2,4,6,8,9,10-hexaaza-1,3,5,7-tetraphophaadamantane 、 copper(l) chloride 以 乙腈 为溶剂， 以45%的产率得到([2,4,6,8,9,10-hexamethyl-2,4,6,8,9,10-hexaaza-1,3,5,7-tetraphosphaadamantane]2(Cu(chloride))2).infin.
  参考文献：
  名称：

  Synthesis and crystal structures of coordination polymers, networks and complexes of an adamantane shaped phosphorus–nitrogen cage ligand and cuprous chloride

  摘要：

  Reactions of cuprous chloride with the phosphorus-nitrogen cage ligand 2,4,6,8,9,10-hexamethyl-2,4,6,8,9,10-hexaaza-1,3,5,7-tetraphosphaadamantane, P-4(NCH3)(6), in acetonitrile form distinct solids depending on the ligand-to-metal ratio. Three structurally characterized compounds include: a solvated 3-D network of formula [P-4(NCH3)(6)](2)(CuCl)(3)(CH3CN)(2); a "ladder-type" Polymer {[mu(2)-P-4(NCH3)(6)](2) (CuCl)(2))}; and a monomeric complex [P-4(NCH3)(6)](2)CuCl. Thermal decomposition of the solvated network results in formation of two more materials [P-4(NCH3)(6)](2)(CuCl)(3), and [P-4(NCH3)(6)](CuCl)(2) that are not isolated from solution reactions. The variety of products isolated based solely on ligand-to-metal ratio suggest that this system participates in solution equilibria common to many phosphorus(III) ligands and multiple solubility equilibria. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.03.019