copper(II) (1-methyl-2((o-thioethyl)phenylazo)imidazole)Cl2 | 887115-11-9

• 英文名称: copper(II) (1-methyl-2((o-thioethyl)phenylazo)imidazole)Cl2
• 英文别名: [Cu(SEtaaiNMe)Cl2]
• CAS: 887115-11-9
• 化学式: C₁₂H₁₄Cl₂CuN₄S
• 分子量: 380.788
• InChiKey: BEZCQLIFYPPJKK-RBIFHYOVSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 1-methyl-2((o-thioethyl)phenylazo)imidazole 以 甲醇 为溶剂， 以60%的产率得到copper(II) (1-methyl-2((o-thioethyl)phenylazo)imidazole)Cl2
  参考文献：
  名称：

  Copper(II) complexes of thioether containing an azoimidazolyl system. X-ray structure of Cu(SEtaaiNEt)Cl2 (SEtaaiNEt=1-ethyl-2-{(o-thioethyl)phenylazo}imidazole)

  摘要：

  The arylthioether diazonium ion is Coupled with imidazole to synthesize tridentate imidizolylizothioether-based NN'S ligands. The reaction Of CuCl2 (.) 2H(2)O with NN'S ligands has synthesized penta-coordinated Cu(NN'S)Cl-2 Compounds. The Structure has been confirmed by an X-ray diffraction study in one case and also by other spectroscopic and magnetic properties. alpha-Diimine (N,N) ligands react with Cu(NN'S)Cl-2 to prepare ternary complexes, [Cu(NN'S)(N,N)](2+). Cu(NN'S)Cl-2 show a Cu-II/Cu-I couple (similar to 0.2 V versus Ag/AgCl). Tertiary complexes show a Cu-II/Cu-I potential at similar to 0.3 V versus Ag/AgCl. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.08.053