tetramethylammonium manganese(II) trichloride | 74241-77-3

• 英文名称: tetramethylammonium manganese(II) trichloride
• CAS: 74241-77-3
• 化学式: C₄H₁₂N*Cl₃Mg
• 分子量: 204.81
• InChiKey: QLEVRSHROVQOQL-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  四甲基氯化铵 、 magnesium(II) chloride hexahydrate 以 水 为溶剂， 生成 tetramethylammonium manganese(II) trichloride
  参考文献：
  名称：

  Exciton trapping in the one‐dimensional antiferromagnet [(CH₃)₄N]MnCl₃

  摘要：

  The dynamics of exciton motion in tetramethylammonium manganese (II) trichloride (TMMC) are investigated in the presence of copper (II) and cobalt (II) traps. Manganese luminescence decay curves are analyzed using several models and at various trap concentrations and temperatures, with the conclusion that trapping does not occur on every encounter. Trapping efficiencies are about 10−4. On-chain transport is found to be incoherent, with hop rates of approximately 1012 s−1 at 273 K and 1011 s−1 at 160 K. The Mn to trap rates and the rate of hopping between trap-limited chain segments are also estimated.

  DOI：

  10.1063/1.452251