FeCl2(N,N'-phenanthroline-5,6-dione)2 | 479065-11-7

• 英文名称: FeCl2(N,N'-phenanthroline-5,6-dione)2
• CAS: 479065-11-7
• 化学式: C₂₄H₁₂Cl₂FeN₄O₄
• 分子量: 547.137
• InChiKey: GHVBYHNVHXHMQX-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  [Fe(N,N'-phenanthroline-5,6-dione)3]Cl2 以 neat (no solvent) 为溶剂， 以97%的产率得到FeCl2(N,N'-phenanthroline-5,6-dione)2
  参考文献：
  名称：

  Transition metal derivatives of 1,10-phenanthroline-5,6-dione: Controlled growth of coordination polynuclear derivatives

  摘要：

  The synthesis and the characterization of several mono- and polymetallic derivatives of 1,10-phenanthroline-5,6,-dione (1) are presented. The reaction of 1 with M(CO)(6) (M = Cr, Mo) gives compounds of general formula M(O, O'-C12H6N2O2)3, M = Cr (2), Mo (3). Compound 3 is also obtained starting from Mo(eta(6)-CH3C6H5)(2), whereas the reaction of Cr(eta(6)-CH3C6H5)(2) with 1 affords the ionic derivative [Cr(eta(6)-CH3C6H5)(2)][C2H6N2O2] (4), which has been studied by EPR spectroscopy and DFT calculations. FeCl2(N,N'-C12H6N2O2)(2) (6), is obtained by thermal decomposition of [Fe(N,N'-C12H6N2O2)(3)]Cl-2 (5).Polymetallic compounds of general formula Cr[O,O'-C12H6N2O2-N,N'-MCl4](3),containing chromium and a Group 4 element M=Ti (7), Zr (8), Hf (9), are prepared from Cr(O,O'-Cl2H6N2O2)(3) and the corresponding MCl4 or MCl4DME. Polynuclear derivatives of iron and chromium of formula [Fe(N,N'-C12H6N2O2-O,O'-CrCl2(THF)(2))(3)][PF6](2) (10), and Cr[O,O'-C12H6N2O2-NN'-FeCl2(THF)](3) (11), are obtained by the reaction of [Fe(N,N'-C12H6N2O2)(3)][PF6](2) with three equivalents of CrCl2(THF)(2) and from Cr(O,O'-Cl2H6N2O2)3 and FeCl2(THF)(1.5), respectively. Compound 11 reacts with 1 (3 equivalents in SYM-C2H2Cl4 or 6 equivalents in ethanol) to give Cr[O,O'-C12H6N2O2-N,N'-FeCl2(N,N'-C12H6N2O2)](3) (12), and [Cr(O,O'-Cl2H6N2O2-N,N'-Fe(N,N'-C12H6N2O2)(2))(3)]Cl-6 (13), respectively. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.04.040