4,5-carboranylene-1,1,3,3-tetramethyl-2-(4-methoxymethyl)-1,3-digermacyclopenane | 383863-75-0

• 英文名称: 4,5-carboranylene-1,1,3,3-tetramethyl-2-(4-methoxymethyl)-1,3-digermacyclopenane
• CAS: 383863-75-0
• 化学式: C₁₅H₃₂B₁₀Ge₂O
• 分子量: 481.708
• InChiKey: SLVYEDLGPQWCHE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-甲氧基苯乙烯 、 [o-bis(dimethylgermyl)carborane]Ni(P(C2H5)3)2 以 甲苯 为溶剂， 以55%的产率得到4,5-carboranylene-1,1,3,3-tetramethyl-2-(4-methoxymethyl)-1,3-digermacyclopenane
  参考文献：
  名称：

  最初的1,3-二聚氰基-2-镍-碳环戊二烯和Ni催化的不饱和有机底物的双重杀菌。

  摘要：

  邻双（二甲基锗基）碳烷与戊烷中的Ni（PEt3）4的反应提供了反应性中间体[o-（GeMe2）2C2B10H10] Ni（PEt3）2 2：2催化的不饱和有机底物的简便双杀菌。报告。

  DOI：

  10.1039/b105026p

文献信息

• Ni-Catalyzed Double Gemylation of Alkynes and Alkenes
  作者：Junghyun Lee、Taegweon Lee、Shim Sung Lee、Ki-Min Park、Sang Ook Kang、Jaejung Ko

  DOI：10.1021/om020399v

  日期：2002.9.1

  The reaction of 1,2-bis(dimethylgermyl)carborane with Ni(PEt3)(4) yielded the cyclic his(germyl)nickel complex 2. 2 was found to be a good catalyst for the double germylation reaction. Thus, the reaction of 1 with RCequivalent toCR' in the presence of a catalytic amount of 2 yielded the six-membered digermyl ring compounds B10H10C2(GeMe2)(2)(RC=CR') (R = R' =Ph (3); R = Ph, R' = H (4); R = R' = Et (5); R = Ph, R' = Me (6); R = R' =: Me (7); R Ph, R'= SiMe3 (8); R = R'= SiMe3 (9); R = R'= CO2Me (10)). In contrast, the reaction of 1 with 1-hexyne under the same reaction conditions yielded the five-membered digermyl ring compound B10H10C2(GeMe2)(2)(C=C(C4H9)H) (11). The intermediate was also found to be a good reactant for the double germylation of some alkenes. Thus, the stoichiometric reaction of 2 with 4-vinylanisole and 1,1-diphenylethylene gave the five-membered digermylene compounds (14 and 15). However, the stoichiometric reaction of 2 with 2,3-dimethylbutadiene afforded a different type of five-membered digerma compound 17 via the 1,4-migration of the hydride. The crystal structures of 2, 6, 12, 14, and 17 are described.