[(η6-p-cymene)RuCl2(κ1-P-3-(diphenylphosphanyl)-2,2-bis(pyrazol-1-yl-methyl) propyl methyl ether)] | 960408-57-5

• 英文名称: [(η6-p-cymene)RuCl2(κ1-P-3-(diphenylphosphanyl)-2,2-bis(pyrazol-1-yl-methyl) propyl methyl ether)]
• CAS: 960408-57-5
• 化学式: C₃₄H₄₁Cl₂N₄OPRu
• 分子量: 724.676
• InChiKey: IXORSHYEYYGXLS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 3-(diphenylphosphanyl)-2,2-bis(pyrazol-1-ylmethyl)propyl methyl ether 以 甲苯 为溶剂， 以81%的产率得到[(η6-p-cymene)RuCl2(κ1-P-3-(diphenylphosphanyl)-2,2-bis(pyrazol-1-yl-methyl) propyl methyl ether)]
  参考文献：
  名称：

  Synthesis and structural characterization of ruthenium(II) complexes bearing phosphine-pyrazolyl based tripod ligands

  摘要：

  Phosphine-pyrazolyl based tripod ligands ROCH2C(CH(2)Pz)(2)(CH2PPh2) ( R = H, Me, allyl; Pz = pyrazol-1-yl) were e. ciently synthesized and characterized. Reactions of these ligands with [Ru(eta(6)-p-cymene)Cl-2](2) afforded complexes of the type [Ru(eta(6)-p-cymene) Cl-2](L) (6-8) in which the ligands exhibit kappa(1)-P-coordination to the metal center. Complex [Ru(eta(6)-p-cymene)Cl-2{Ph2PCH2C( CH2OH)(CH(2)Pz)(2)}] (6) underwent chloride-dissociation in CH2Cl2/MeCN to give complex [RuCl(eta(6)-p-cymene){kappa(2)(P,N)-Ph2PCH2C( CH2OH)(CH(2)Pz)(2)}][Cl] (9). Complexes 6-9 demonstrated poor to moderate catalytic activity in the transfer hydrogenation of acetophenone. All these complexes were fully characterized by analytical and spectroscopic methods and their molecular structures were determined by X-ray crystallographic study. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.08.025