[Sn(CH3)2(acetone N(4)-phenylthiosemicarbazone(-1H))Cl] | 658704-63-3

• 英文名称: [Sn(CH3)2(acetone N(4)-phenylthiosemicarbazone(-1H))Cl]
• 英文别名: [SnMe2(aptsc)Cl]
• CAS: 658704-63-3
• 化学式: C₁₂H₁₈ClN₃SSn
• 分子量: 390.524
• InChiKey: SVZFSTFQFXRCLK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二甲基二氯化锡 、 丙酮 4-苯基-3-缩氨基硫脲 以 乙醇 为溶剂， 以63%的产率得到[Sn(CH3)2(acetone N(4)-phenylthiosemicarbazone(-1H))Cl]
  参考文献：
  名称：

  Diorganotin(IV) complexes with acetone N(4)-phenylthiosemicarbazone (Haptsc) as ligand. The crystallographic structures of [Sn(CH3)2(aptsc)X] (X=Cl and Br)

  摘要：

  The reaction of Haptsc with SnMe2Cl2 and SnMe2Br2 yielded [Sn(CH3)(2)(aptsc)Cl] (1) and [Sn(CH3)(2)(aptsc)Br] (2), respectively. The complexes were characterized by IR and NMR (H-1, Sn-119) spectroscopic. methods, elemental analysis and X-ray crystal structure determination. The X-ray study revealed that both complexes possess a trigonal bipyramidal geometry. (1) crystallizes in the orthorhombic crystal system, space group P2(1)2(1)2(1), with a = 10.5157(6), b = 12.2085(15), c = 12.496(3) Angstrom, V = 1604.2 Angstrom(3) and Z = 4. (2) crystallizes in the monoclinic crystal system, space group P2(1)/c, with a = 17.3253(17), b = 7.2323(6), c = 13.3527(15) Angstrom, beta = 108.560(10)degrees, V = 1586.1 Angstrom(3) and Z = 4. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2003.08.009