| 1609138-24-0

• CAS: 1609138-24-0
• 化学式: C₁₉H₃₂GeN₂OTe
• 分子量: 504.666
• InChiKey: ZABCTTAAGMHFOX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  碲化氢 、 [(i-Bu)2aminotroponiminate]GeO-t-Bu 以 甲苯 为溶剂， 反应 6.0h， 以98%的产率得到
  参考文献：
  名称：

  Are Ligand-Stabilized Carboxylic Acid Derivatives with Ge═Te Bonds Isolable?

  摘要：

  The stability of ligand-stabilized carboxylic acid derivatives (such as esters, amides, anhydrides, and acid halides) with terminal Ge=Te bonds is highly questionable as there is no report on such compounds. Nevertheless, we are able to isolate germatelluroester [LGe(Te)Ot-Bu] (4), germatelluroamide [LGe(Te)N(SiMe3)(2)] (5), and germatelluroacid anhydride [LGe(Te)OGe(Te)L] (6) complexes (L = aminotroponiminate (ATI)) as stable species. Consequently, the synthetic details, structural characterization, and UV-vis spectroscopic and theoretical studies on them are reported for the first time.

  DOI：

  10.1021/ic500116f