chloro-(N,N’-di(benzyl)-N,N’-bis(2-pyridylmethyl)-1,2-cyclohexanediamine)iron(II) hexafluoroantimonate | 1608496-68-9

• 英文名称: chloro-(N,N’-di(benzyl)-N,N’-bis(2-pyridylmethyl)-1,2-cyclohexanediamine)iron(II) hexafluoroantimonate
• CAS: 1608496-68-9
• 化学式: C₃₂H₃₆ClFeN₄*F₆Sb
• 分子量: 803.705
• InChiKey: HDHONNDXWZEKNS-LIDQEFFQSA-G

反应信息

• 作为产物：
  描述：

  silver hexafluoroantimonate 、 dichloro-(N,N’-di(benzyl)-N,N’-bis(2-pyridylmethyl)-1,2-cyclohexanediamine)iron(II) 以 乙腈 为溶剂， 反应 96.0h， 以66%的产率得到chloro-(N,N’-di(benzyl)-N,N’-bis(2-pyridylmethyl)-1,2-cyclohexanediamine)iron(II) hexafluoroantimonate
  参考文献：
  名称：

  Kinetic Analysis of the Formation and Decay of a Non-Heme Ferric Hydroperoxide Species Susceptible to O–O Bond Homolysis

  摘要：

  The formation of a ferric hydroperoxide species from [Fe(bbpc)(MeCN)(2)](2+) (bbpc = N,N'-dibenzyl-N,N'-bis(2-pyridylmethyl)-1,2-cyclohexanediamine) and its subsequent decomposition were analyzed kinetically. The rate of decay is not strongly influenced by the presence of either water or substrate, suggesting that the ferric hydroperoxide degrades through O-O bond homolysis and is not the relevant metal-based oxidant in the observed catalysis of C-H activation. The rate law corresponding to the complex's formation from O-2 is consistent with the intermediacy of a mononuclear ferric superoxo species.

  DOI：

  10.1021/ic5003786