| 158043-40-4

• CAS: 158043-40-4
• 化学式: C₁₁H₁₀Br₂N₄Pd
• 分子量: 464.455
• InChiKey: XLRXTMIUWYQRMH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  在 KBr or NH₄Br 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Design, synthesis and spectroscopic characterization of palladium(II) and platinum(II) complexes of pyrazole-derived ligands with potential anti-tumour properties in its historical perspective

  摘要：

  The synthesis and physico-chemical identification of a host of new palladium(II) and platinum(II) complexes with two strategically designed pyrazole-derived ligands, 3,5-dimethyl-1-(0-aminophenyl)pyrazole (DApPz) and 5-methyl-3-(2'-benzimidazolyl) pyrazole (MBP), are described. All the reported non-electrolytic monochelates, M(DApPz)X2 and M(MBP)X2 (M = Pd(II) or Pt(II), X = a counterion) are planar species, as ascertained from electronic spectral features together with the LF parameters. The proven (N-N) bidentate nature of the pyrazole-based primary ligand(s) along with relevant IR data classify the complexes as cis derivatives. H-1 NMR data of the uncomplexed ligand(s) and of the reported diamagnetic Pd(II) and Pt(II) species (recorded in DMSO-d6 at 300 MHz) are commensurate with the conclusions (drawn from IR spectral features) that primary ligand DApPz is bonded to Pd(II) or Pt(II) through the pyrazolyl (ring) nitrogen and the amino nitrogen, and that MBP functions through N(2) of the pyrazole and N(3) of the imidazole moieties in complexation.

  DOI：

  10.1016/s0277-5387(00)83485-3