[Ru(8-hydroxyquinolinato)2(2,5-norbornadiene)]BPh4 | 1144514-67-9

• 英文名称: [Ru(8-hydroxyquinolinato)2(2,5-norbornadiene)]BPh4
• CAS: 1144514-67-9
• 化学式: C₂₄H₂₀B*C₂₅H₂₀N₂O₂Ru
• 分子量: 800.75
• InChiKey: FDYIMINTFQKJAJ-LJVBVETGSA-L

反应信息

• 作为反应物：
  描述：

  [Ru(8-hydroxyquinolinato)2(2,5-norbornadiene)]BPh4 在 CN^(1-) 作用下， 以 not given 为溶剂， 生成 cis,trans-Ru(8-hydroxyquinolinato)2(2,5-norbornadiene)
  参考文献：
  名称：

  8-Quinolinolato complexes of ruthenium(II) and (III)

  摘要：

  Reduction of RuQ(3) (1a, Q = 8-quinolinolato) with Zn/Hg in the presence of various pi-acceptor ligands in ethanol affords RuQ(2)L(2) (L-2 = (dimethylsulfoxide)(2) (2); (4-picoline)(2) (3); N,N'-dimethyl-1,4-diazabuta-1,3-diene, dab (4); cyclooctadiene, COD (5); norborna-2,5-diene, nbd (6)). Compound 6 is isolated as an equimolar mixture of cis, trans (6a) and trans, cis (6b) isomers, which can be separated by column chromatography. DFT calculations have been performed on 6a and 6b. Oxidation of 3 and 6b affords the corresponding ruthenium(III) species 7 and 8, respectively. The structures of 2, 3, 4 and 6 have been determined by X-ray crystallography. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.05.036
• 作为产物：
  描述：

  cis,trans-Ru(8-hydroxyquinolinato)2(2,5-norbornadiene) 、 四苯硼钠 在 FeCl₃*6H₂O 作用下， 以 甲醇 为溶剂， 以75%的产率得到[Ru(8-hydroxyquinolinato)2(2,5-norbornadiene)]BPh4
  参考文献：
  名称：

  8-Quinolinolato complexes of ruthenium(II) and (III)

  摘要：

  Reduction of RuQ(3) (1a, Q = 8-quinolinolato) with Zn/Hg in the presence of various pi-acceptor ligands in ethanol affords RuQ(2)L(2) (L-2 = (dimethylsulfoxide)(2) (2); (4-picoline)(2) (3); N,N'-dimethyl-1,4-diazabuta-1,3-diene, dab (4); cyclooctadiene, COD (5); norborna-2,5-diene, nbd (6)). Compound 6 is isolated as an equimolar mixture of cis, trans (6a) and trans, cis (6b) isomers, which can be separated by column chromatography. DFT calculations have been performed on 6a and 6b. Oxidation of 3 and 6b affords the corresponding ruthenium(III) species 7 and 8, respectively. The structures of 2, 3, 4 and 6 have been determined by X-ray crystallography. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.05.036