[N,N'-bis(2-hydroxy-5-methoxybenzylidene)-propane-1,2-diamine](aqua)(pyridine) manganese(III) hexafluorophosphate | 1312290-52-0

• 英文名称: [N,N'-bis(2-hydroxy-5-methoxybenzylidene)-propane-1,2-diamine](aqua)(pyridine) manganese(III) hexafluorophosphate
• CAS: 1312290-52-0
• 化学式: C₂₄H₂₇MnN₃O₅*F₆P
• 分子量: 637.398
• InChiKey: JPWKKDSWGVXJQV-NMQVGFBHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 吡啶 、 N,N'-bis(2-hydroxy-5-methoxybenzylidene)-propane-1,2-diamine 、 manganese(II) acetate dihydrate 在 air 作用下， 以 乙醇 为溶剂， 以83%的产率得到[N,N'-bis(2-hydroxy-5-methoxybenzylidene)-propane-1,2-diamine](aqua)(pyridine) manganese(III) hexafluorophosphate
  参考文献：
  名称：

  Syntheses, spectral, electrochemical and thermal studies of mononuclear manganese(III) complexes with ligands derived from 1,2-propanediamine and 2-hydroxy-3 or 5-methoxybenzaldehyde: Self-assembled monolayer formation on nanostructure zinc oxide thin film

  摘要：

  Mononuclear Mn(III) complexes have been prepared via the Mn(II) reaction of an equimolar of Schiff-bases derived from reaction of 2-hydroxy-3-methoxybenzaldehyde or 2-hydroxy-5-methoxybenzaldehyde with 1,2-diaminopropane. Axial ligands L include: pyridine (py) and H2O. The resulting complexes have been characterized by FT-IR and UV-vis spectroscopy. The crystal structures of the complexes were determined and indicate that in the solid state the complex adopts a slightly distorted octahedral environment of the imine N and hydroxo O with the two axial ligands. The electrochemical reduction of these complexes at a glassy carbon electrode in acetonitrile solution indicates that the first reduction process corresponding to Mn-III-Mn-II is electrochemically quasi-reversible. Thermal stability of these complexes was determined by TG and DTG. Layers of these complexes were formed on nanostructure zinc oxide thin film and a red shift was observed when zinc oxide thin film is modified by complex. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2011.03.055