[Co(XBP)Br2] | 801293-55-0

• 英文名称: [Co(XBP)Br2]
• 英文别名: [Co(N,N'-p-phenylenedimethylenebis(pyridin-4-one))Br2]
• CAS: 801293-55-0
• 化学式: C₁₈H₁₆Br₂CoN₂O₂
• 分子量: 511.138
• InChiKey: GPMNENHXPKJZLX-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  cobalt(II) bromide hexahydrate 、 N,N'-p-phenylenedimethylenebis(pyridin-4-one) tetrahydrate 以 乙醇 为溶剂， 以100%的产率得到[Co(XBP)Br2]
  参考文献：
  名称：

  Synthesis and Spectroscopic Studies of Metal Complexes of N,N′‐p‐Phenylenedimethylenebis(pyridin‐4‐one) with d‐ and f‐Block Metal Ions

  摘要：

  The preparations are reported for a range of complexes of the ligand N,N'-p-phenylenedimethylenebis(pyridin-4-one) (XBP) with the d-block ions Mn(II) to Zn(II) and also with Cd(II), Y(III), and the lanthanide ions. Relevant solid state EPR, electronic and far-IR spectra are reported and interpreted in terms of the metal ion coordination geometries and, where appropriate, the likely long-range polymeric structures of the compounds. The value of the zero-field splitting (zfs) parameter, D = 0.069 cm(-1), obtained from the S = I type EPR spectrum of the compound ([Cu-2(XBP)(3)(NO3)(2)](NO3)(2).2H(2)O)(n) is compared with those of other compounds involving discrete Cu...Cu dimer interaction. The results of luminescence measurements on the complexes of Sm(III), Eu(III), Tb(III), and Dy(III) are also given.

  DOI：

  10.1081/sim-120039269