2-[(N,N-dimethylaminomethyl)phenyl]dimethylstannylfluoride | 712351-38-7

• 英文名称: 2-[(N,N-dimethylaminomethyl)phenyl]dimethylstannylfluoride
• 英文别名: (2-(Me2NCH2C6H4)dimethyltin(IV) fluoride
• CAS: 712351-38-7
• 化学式: C₁₁H₁₈FNSn
• 分子量: 301.979
• InChiKey: IIEJVMBNSYVJKR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium fluoride 、 [2-(Me2NCH2)C6H4]Me2SnCl 以 甲醇 、 二氯甲烷 、 水 为溶剂， 以89%的产率得到2-[(N,N-dimethylaminomethyl)phenyl]dimethylstannylfluoride
  参考文献：
  名称：

  含有 2-(Me2NCH2)C6H4 基团的超配位有机锡 (IV) 卤化物：{2-(Me2NCH2)C6H4}2SnX2 (X = F, Cl, Br, I) 和 {2-(Me2NCH2)C6H4}R2SnX (R = Me, Ph；X = F、Cl、Br、I) 及其溶液行为和固态、基于氢键的超分子结构

  摘要：

  超配位的二有机锡和三有机锡 (iv) 氯化物 [{2-(Me 2 NCH 2 )C 6 H 4 } 2 SnCl 2 ] (la) 和 [{2-(Me 2 NCH 2 )C 6 H 4 }-R 2 SnCl] [R = Me (2a), Ph (3a)] 通过用 [Li{2-(Me2NCH2)C 6 H 4 }] 处理 SnCl 4 或 R 2 SnCl 2 来制备。有机锡 (iv) 氯化物和适当的卤化钾之间的卤化物交换反应得到 [{2-(Me 2 NCH 2 )-C 6 H 4 } 2 SnX 2 ] [X = F (1b), I (1d)] , [{2-(Me 2 NCH 2 )C 6 H 4 }-Me 2 SnX] [X = F (2b), Br (2c), I (2d)] 和 [{2-(Me 2 NCH 2 ) -C 6 H 4 }Ph 2 SnX] [X = F (3b), I (3d)]。它们的溶液行为通过多核（

  DOI：

  10.1002/ejic.200501018

文献信息

• Monomeric Triorganotin(IV) Fluorides Containing a C,N-Chelating Ligand
  作者：Josef Bareš、Petr Novák、Milan Nádvorník、Roman Jambor、Tomáš Lébl、Ivana Císařová、Aleš Růžička、Jaroslav Holeček

  DOI：10.1021/om049912q

  日期：2004.6.1

  The set of four triorganotin(IV) fluorides of general formula 2-[(CH3)(2)NCH2]C6H4}R2SnF, where R is Me (5), n-Bu (6), t-Bu (7), and Ph (8), respectively, has been prepared and characterized using NMR and ESI-MS techniques. The structures of crystalline compounds 5 and 8 were determined using X-ray methods. All compounds are monomeric both in solution using different solvents and in the solid state. The tin central atom is five-coordinated with all carbon atoms in equatorial positions and fluorine and nitrogen, from the intramolecularly coordinated dimethylamino group, in the axial positions of the distorted trigonal bipyramid. The ability of compounds 6 and 8 to perform fluorination of organometallic chlorides was tested on titanocene dichloride. A quantitative yield Of CP2TiF2 was obtained.