| 126453-72-3

• CAS: 126453-72-3；22651-31-6；22657-35-8
• 化学式: C₁₄H₁₆Cl₄S₂Sn
• 分子量: 508.935
• InChiKey: SHRQCYGRNKNOCM-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  茴香硫醚 、 四氯化锡 以 四氯化碳 为溶剂， 生成
  参考文献：
  名称：

  Electron density redistribution on complexation in non-transition element complexes

  摘要：

  Complexes of tin, antimony, silicon, germanium, iodine, boron and titanium halogenides with organic ligands were investigated using nuclear quadrupole resonance (NQR) and X-ray fluorescence spectroscopies, and Mossbauer effect and quantum-chemical calculations. A discussion of results which we obtained previously as well as literature data is included. The correlations between Cl-35 NQR and ClKalpha line shifts in SnCl4L2, SbCl5L and TiCl4L2 complexes were obtained. The geometry of the acceptor was found to influence the value of the effective charge on the chlorine atom (q(Cl)) in SnCl4L2 complexes, but not to influence the chlorine atom in TiCl4L2 complexes. Values of q(Sn) and q(Sb) were calculated from Mossbauer isomer shifts in the SnCl4L2 and SbCl5L complexes. Electron-density transfer from the ligand to the vacant d orbital of the central atom on complexation was observed.

  DOI：

  10.1016/0022-2860(93)80185-x