(1,1'-di(2-tert-butyl-6-diphenylphosphiniminophenoxy)ferrocene)In(OPh) | 1309956-43-1

• 英文名称: (1,1'-di(2-tert-butyl-6-diphenylphosphiniminophenoxy)ferrocene)In(OPh)
• CAS: 1309956-43-1
• 化学式: C₆₀H₅₇FeInN₂O₃P₂
• 分子量: 1086.74
• InChiKey: GAOBBYXCJXUAEX-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate 、 (1,1'-di(2-tert-butyl-6-diphenylphosphiniminophenoxy)ferrocene)In(OPh) 以 甲苯 为溶剂， 生成 [1,1'-di(2-tert-butyl-6-diphenylphosphiniminophenoxy)ferrocenium)In(OPh)][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate]
  参考文献：
  名称：

  Redox Control of a Ring-Opening Polymerization Catalyst

  摘要：

  The activity of an yttrium alkoxide complex supported by a ferrocene-based ligand was controlled using redox reagents during the ring-opening polymerization of L-lactide. The oxidized complex was characterized by X-ray crystallography and H-1 NMR, XANES, and Mossbauer spectroscopy. Switching in situ between the oxidized and reduced yttrium complexes resulted in a change in the rate of polymerization of L-lactide. Synthesized polymers were analyzed by gel permeation chromatography. Polymerization of trimethylene carbonate was also performed with the reduced and oxidized forms of an indium alkoxide complex. The indium system showed the opposite behavior to that of yttrium, revealing a metal-based dependency on the rate of polymerization.

  DOI：

  10.1021/ja2036089
• 作为产物：
  描述：

  (1,1'-di(2-tert-butyl-6-diphenylphosphiniminophenoxy)ferrocene)InCl 、 sodium phenoxide 以 乙醚 为溶剂， 以85%的产率得到(1,1'-di(2-tert-butyl-6-diphenylphosphiniminophenoxy)ferrocene)In(OPh)
  参考文献：
  名称：

  Redox Control of a Ring-Opening Polymerization Catalyst

  摘要：

  The activity of an yttrium alkoxide complex supported by a ferrocene-based ligand was controlled using redox reagents during the ring-opening polymerization of L-lactide. The oxidized complex was characterized by X-ray crystallography and H-1 NMR, XANES, and Mossbauer spectroscopy. Switching in situ between the oxidized and reduced yttrium complexes resulted in a change in the rate of polymerization of L-lactide. Synthesized polymers were analyzed by gel permeation chromatography. Polymerization of trimethylene carbonate was also performed with the reduced and oxidized forms of an indium alkoxide complex. The indium system showed the opposite behavior to that of yttrium, revealing a metal-based dependency on the rate of polymerization.

  DOI：

  10.1021/ja2036089