| 1150676-30-4

• CAS: 1150676-30-4
• 化学式: C₁₅H₁₅Cl₂CuN₃
• 分子量: 371.756
• InChiKey: UELYUVSEZQULNQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 2-(3',5'-dimethylpyrazol-1'-yl)-4-methylquinoline 以 乙醇 、 二氯甲烷 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Fe(II) complex with chiral pyrazolylquinoline L and Fe(II), Co(II), and Cu(II) complexes with achiral pyrazolylquinoline L1: Synthesis and properties. The crystal structures of [ML1Cl2] (M = Fe, Co, and Cu)

  摘要：

  The complexes FeLCl2 (I), [(FeLCl2)-Cl-1] (II), [(CoLCl2)-Cl-1] (III), and [(CuLCl2)-Cl-1] (IV) (where L and L-1 are chiral and achiral pyrazolylquinolines, respectively) were obtained. Complexes II-IV were structurally characterized by single-crystal X-ray diffraction analysis. Crystals of complexes II and III are triclinic (space group P) and crystals of complex IV are monoclinic (space group P2(1)/n). Structures II-IV are built from discrete mononuclear acentric molecules. In these complexes, the M2+ ion (M = Fe, Co, and Cu) coordinates two N atoms of the bidentate chelating ligand L-1 and two Cl atoms. The coordination cores MCl2N2 are distorted tetrahedra. For complexes I and II, mu(eff) = 5.05 and 5.07 mu(B), respectively, correspond to the high-spin configuration d(6). For complex III, mu(eff) = 4.51 mu(B) (high-spin configuration d(7)) and for complex IV, mu(eff) = 1.80 mu(B) (configuration d(9)).

  DOI：

  10.1134/s1070328408040076