[Fe(1,2-[bis(6'-pyridine-2'-carboxamido)-ethane]benzene)(2-)Cl] | 1175571-30-8

• 英文名称: [Fe(1,2-[bis(6'-pyridine-2'-carboxamido)-ethane]benzene)(2-)Cl]
• CAS: 1175571-30-8
• 化学式: C₂₀H₁₄ClFeN₄O₂
• 分子量: 433.657
• InChiKey: OPPYYQQLKLPDFD-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  iron(III) chloride hexahydrate 、 1,2-[bis(6'-pyridine-2'-carboxamido)-ethane]benzene 在 NaOOCCH₃ 作用下， 以 甲醇 为溶剂， 以75%的产率得到[Fe(1,2-[bis(6'-pyridine-2'-carboxamido)-ethane]benzene)(2-)Cl]
  参考文献：
  名称：

  Synthesis, crystal structures and catalytic abilities of new macrocyclic bis-pyridineamido MnIII and FeIII complexes

  摘要：

  A new macrocyclic ligand H2L (H2L = 1,2-[bis(6'-pyridine-2'-carboxamido)-ethane]benzene) has been designed and synthesized by condensation of pyridine-carboxylic acid and diamine. Its Mn(III) and Fe(III) complexes, [Mn(L)Cl (DMF)] and [Fe(L)Cl], were prepared and respectively characterized by IR, UV-Vis, ESI-Mass, elemental analysis and X-ray single crystal diffraction. The catalytic abilities of them were examined, and up to 95% yield was achieved in epoxidation of styrene. The preliminary investigation of catalytic mechanism by manganese complex was carried out, suggesting the involvement of Mn(V) oxo species during catalysis. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.03.019