[PdCl2(1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(methoxycarbonyl)-1,4-diarsinine)2] | 1015814-17-1

• 英文名称: [PdCl2(1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(methoxycarbonyl)-1,4-diarsinine)2]
• CAS: 1015814-17-1
• 化学式: C₂₈H₃₆As₄Cl₂O₁₆Pd
• 分子量: 1105.6
• InChiKey: ZHTYBRSIICAKMS-HUQQVXAYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(methoxycarbonyl)-1,4-diarsinine 以 甲苯 为溶剂， 以99%的产率得到[PdCl2(1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(methoxycarbonyl)-1,4-diarsinine)2]
  参考文献：
  名称：

  Stoichiometric Complexation of Palladium(II) with 1,4-Dihydro-1,4-diarsinine as a Rigid Symmetrical Bidentate Ligand

  摘要：

  Bimetallic and monometallic palladium(II) complexes with 1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(methoxycarbonyl)-1,4-diarsinine (1) were selectively obtained by stoichiometric addition of PdCl2(PhCN)(2) to 1 as [Pd2Cl4(1)(2)] (2) (yield 83%) and [PdCl2(1)(2)] (3) (yield 99%), respectively. The structures of [Pd2Cl4(1)(2)] (2) and [PdCl2(1)(2)] (3) were confirmed by H-1 NMR spectra, X-ray crystallography, and elemental analysis.

  DOI：

  10.1021/om8000179