[(2,6-dibenzhydryl-N-(2-(2,6-diethyl-4-methylphenylimino)acenaphthylenylidene)-4-methylbenzenamine)NiBr2] | 1285664-53-0

• 英文名称: [(2,6-dibenzhydryl-N-(2-(2,6-diethyl-4-methylphenylimino)acenaphthylenylidene)-4-methylbenzenamine)NiBr2]
• CAS: 1285664-53-0
• 化学式: C₅₆H₄₈Br₂N₂Ni
• 分子量: 967.509
• InChiKey: CBYYAPRJQDGDAM-HXZYNKONSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙二醇二甲醚溴化镍 、 2,6-dibenzhydryl-N-(2-(2,6-diethyl-4-methylphenylimino)acenaphthylenylidene)-4-methylbenzenamine 以 二氯甲烷 为溶剂， 以75%的产率得到[(2,6-dibenzhydryl-N-(2-(2,6-diethyl-4-methylphenylimino)acenaphthylenylidene)-4-methylbenzenamine)NiBr2]
  参考文献：
  名称：

  2,6-Dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamine Nickel Dibromides: Synthesis, Characterization, and Ethylene Polymerization

  摘要：

  A series of 2,6-dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamines (L1-L5) and the nickel(II) dibromide complexes thereof (C1-C5) were synthesized and. fully characterized. The molecular structures of representative complexes were determined by single-crystal X-ray diffraction and revealed a distorted-pyramidal geometry at nickel. All nickel(II) pro catalysts exhibited very high activity for the polymerization of ethylene, with activities as high as the range of 10(7) g of PE (mol of Ni)(-1) h(-1)

  DOI：

  10.1021/om200154a